Wehenkel Dominique Joseph, Bointon Thomas Hardisty, Booth Tim, Bøggild Peter, Craciun Monica Felicia, Russo Saverio
Centre for Graphene Science, College of Engineering, Mathematics and Physical Sciences, University of Exeter, Exeter EX4 4QF, UK.
Center for Nanostructured Graphene (CNG), Department of Micro- and Nanotechnology Engineering, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.
Sci Rep. 2015 Jan 8;5:7609. doi: 10.1038/srep07609.
We present the first systematic study of the stability of the structure and electrical properties of FeCl3 intercalated few-layer graphene to high levels of humidity and high temperature. Complementary experimental techniques such as electrical transport, high resolution transmission electron microscopy and Raman spectroscopy conclusively demonstrate the unforseen stability of this transparent conductor to a relative humidity up to 100% at room temperature for 25 days, to a temperature up to 150°C in atmosphere and to a temperature as high as 620°C in vacuum, that is more than twice higher than the temperature at which the intercalation is conducted. The stability of FeCl3 intercalated few-layer graphene together with its unique values of low square resistance and high optical transparency, makes this material an attractive transparent conductor in future flexible electronic applications.
我们首次对插层有FeCl₃的少层石墨烯的结构和电学性质在高湿度和高温条件下的稳定性进行了系统研究。诸如电输运、高分辨率透射电子显微镜和拉曼光谱等互补性实验技术确凿地证明了这种透明导体在室温下相对湿度高达100%的环境中保持25天、在大气中温度高达150°C以及在真空中温度高达620°C时具有意想不到的稳定性,该温度比进行插层时的温度高出两倍多。插层有FeCl₃的少层石墨烯的稳定性及其低方阻和高光学透明度的独特值,使其成为未来柔性电子应用中极具吸引力的透明导体。