Schornbaum Julia, Zakharko Yuriy, Held Martin, Thiemann Stefan, Gannott Florentina, Zaumseil Jana
Department of Materials Science and Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg , D-91058 Erlangen, Germany.
Nano Lett. 2015 Mar 11;15(3):1822-8. doi: 10.1021/nl504582d. Epub 2015 Feb 5.
For the application of colloidal semiconductor quantum dots in optoelectronic devices, for example, solar cells and light-emitting diodes, it is crucial to understand and control their charge transport and recombination dynamics at high carrier densities. Both can be studied in ambipolar, light-emitting field-effect transistors (LEFETs). Here, we report the first quantum dot light-emitting transistor. Electrolyte-gated PbS quantum dot LEFETs exhibit near-infrared electroluminescence from a confined region within the channel, which proves true ambipolar transport in ligand-exchanged quantum dot solids. Unexpectedly, the external quantum efficiencies improve significantly with current density. This effect correlates with the unusual increase of photoluminescence quantum yield and longer average lifetimes at higher electron and hole concentrations in PbS quantum dot thin films. We attribute the initially low emission efficiencies to nonradiative losses through trap states. At higher carrier densities, these trap states are deactivated and emission is dominated by trions.
对于胶体半导体量子点在光电器件(例如太阳能电池和发光二极管)中的应用而言,了解并控制其在高载流子密度下的电荷传输和复合动力学至关重要。这两者均可在双极性发光场效应晶体管(LEFET)中进行研究。在此,我们报道了首个量子点发光晶体管。电解质栅控PbS量子点LEFET在沟道内的受限区域表现出近红外电致发光,这证明了配体交换量子点固体中真正的双极性传输。出乎意料的是,外部量子效率随电流密度显著提高。这种效应与PbS量子点薄膜中较高电子和空穴浓度下光致发光量子产率的异常增加以及更长的平均寿命相关。我们将最初较低的发射效率归因于通过陷阱态的非辐射损失。在较高载流子密度下,这些陷阱态失活,发射由三重态主导。