Department of Materials Science and Engineering and ‡Department of Chemistry and Biochemistry, UCLA , Los Angeles, California 90095-1595, United States.
Nano Lett. 2015 Mar 11;15(3):1911-7. doi: 10.1021/nl504764m. Epub 2015 Feb 17.
Single-layer and few-layer transition metal dichalcogenides have been extensively studied for their electronic properties, but their energy-storage potential has not been well explored. This paper describes the structural and electrochemical properties of few-layer TiS2 nanocrystals. The two-dimensional morphology leads to very different behavior, compared to corresponding bulk materials. Only small structural changes occur during lithiation/delithiation and charge storage characteristics are consistent with intercalation pseudocapacitance, leading to materials that exhibit both high energy and power density.
单层和少数层过渡金属二硫属化物因其电子特性而得到广泛研究,但它们的储能潜力尚未得到充分探索。本文描述了少数层 TiS2 纳米晶体的结构和电化学性质。与相应的体材料相比,二维形态导致了非常不同的行为。在锂化/脱锂过程中只有很小的结构变化,电荷存储特性与插层赝电容一致,从而得到了同时具有高能量和功率密度的材料。