酚类对烯丙基氧化物的区域发散性加成反应。
Regiodivergent addition of phenols to allylic oxides.
作者信息
Vaccarello David N, Moschitto Matthew J, Lewis Chad A
机构信息
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, United States.
出版信息
J Org Chem. 2015 May 15;80(10):5252-9. doi: 10.1021/acs.joc.5b00671. Epub 2015 May 1.
Abstract
The regiodivergent addition of substituted phenols to allylic oxides has been demonstrated using C2-symmetric palladium complexes. Complex phenol donors tyrosine, estradiol, and griseofulvin follow the predictive model.
摘要
已证明使用C2对称钯配合物可实现取代酚与烯丙基氧化物的区域发散加成。复杂的酚供体酪氨酸、雌二醇和灰黄霉素符合预测模型。
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本文引用的文献
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