锰（I）催化杂芳烃的 C-H 氨甲酰化反应。
Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes.
机构信息
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/.
出版信息
Angew Chem Int Ed Engl. 2015 Nov 16;54(47):14137-40. doi: 10.1002/anie.201507087. Epub 2015 Sep 29.
A versatile manganese(I) catalyst was employed in C-H aminocarbonylation reactions of heteroarenes with aryl as well as with alkyl isocyanates using a removable directing group approach. Detailed experimental mechanistic studies were suggestive of an organometallic C-H manganesation step, followed by a rate-determining migratory insertion.
一种多功能的锰（I）催化剂被用于杂芳环与芳基以及烷基异氰酸酯的 C-H 氨甲酰化反应，使用可去除导向基团的方法。详细的实验机理研究表明，该反应经历了一个有机金属 C-H 锰化步骤，随后是一个速率决定的迁移插入步骤。
Zotero 插件