Hong Young Joon, Lee Chul-Ho, Yoo Jinkyoung, Kim Yong-Jin, Jeong Junseok, Kim Miyoung, Yi Gyu-Chul
Faculty of Nanotechnology &Advanced Materials Engineering, Graphene Research Institute, and Hybrid Materials Research Center, Sejong University, Seoul 143-747, Korea.
KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul 136-701, Korea.
Sci Rep. 2015 Dec 9;5:18020. doi: 10.1038/srep18020.
Integration of nanostructure lighting source arrays with well-defined emission wavelengths is of great importance for optoelectronic integrated monolithic circuitry. We report on the fabrication and optical properties of GaN-based p-n junction multishell nanotube microarrays with composition-modulated nonpolar m-plane InxGa1-xN/GaN multiple quantum wells (MQWs) integrated on c-sapphire or Si substrates. The emission wavelengths were controlled in the visible spectral range of green to violet by varying the indium mole fraction of the InxGa1-xN MQWs in the range 0.13 ≤ x ≤ 0.36. Homogeneous emission from the entire area of the nanotube LED arrays was achieved via the formation of MQWs with uniform QW widths and composition by heteroepitaxy on the well-ordered nanotube arrays. Importantly, the wavelength-invariant electroluminescence emission was observed above a turn-on of 3.0 V because both the quantum-confinement Stark effect and band filling were suppressed due to the lack of spontaneous inherent electric field in the m-plane nanotube nonpolar MQWs. The method of fabricating the multishell nanotube LED microarrays with controlled emission colors has potential applications in monolithic nonpolar photonic and optoelectronic devices on commonly used c-sapphire and Si substrates.
集成具有明确发射波长的纳米结构光源阵列对于光电集成单片电路至关重要。我们报道了基于GaN的p-n结多壳纳米管微阵列的制备及其光学性质,该微阵列具有集成在c-蓝宝石或Si衬底上的成分调制非极性m面InxGa1-xN/GaN多量子阱(MQW)。通过在0.13≤x≤0.36范围内改变InxGa1-xN MQW的铟摩尔分数,发射波长被控制在绿色到紫色的可见光谱范围内。通过在有序纳米管阵列上进行异质外延形成具有均匀量子阱宽度和成分的MQW,实现了纳米管LED阵列整个区域的均匀发射。重要的是,在3.0 V的开启电压以上观察到波长不变的电致发光发射,这是因为m面纳米管非极性MQW中缺乏自发固有电场,抑制了量子限制斯塔克效应和能带填充。制备具有可控发射颜色的多壳纳米管LED微阵列的方法在常用的c-蓝宝石和Si衬底上的单片非极性光子和光电器件中具有潜在应用。