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从摩洛哥橄榄油厂废水中提取油酸。

Extraction of Oleic Acid from Moroccan Olive Mill Wastewater.

作者信息

Elkacmi Reda, Kamil Noureddine, Bennajah Mounir, Kitane Said

机构信息

Department of Chemistry and Valorisation, Faculty of Sciences Ain-Chock, HASSAN II University of Casablanca, BP 5366 Maarif, Casablanca, Morocco; Process Engineering and Environment Laboratory (PEEL), High School of Technology of Casablanca, HASSAN II University of Casablanca, BP 8012 Oasis, Casablanca, Morocco.

Process Engineering and Environment Laboratory (PEEL), High School of Technology of Casablanca, HASSAN II University of Casablanca, BP 8012 Oasis, Casablanca, Morocco.

出版信息

Biomed Res Int. 2016;2016:1397852. doi: 10.1155/2016/1397852. Epub 2016 Jan 10.

Abstract

The production of olive oil in Morocco has recently grown considerably for its economic and nutritional importance favored by the country's climate. After the extraction of olive oil by pressing or centrifuging, the obtained liquid contains oil and vegetation water which is subsequently separated by decanting or centrifugation. Despite its treatment throughout the extraction process, this olive mill wastewater, OMW, still contains a very important oily residue, always regarded as a rejection. The separated oil from OMW can not be intended for food because of its high acidity of 3.397% which exceeds the international standard for human consumption defined by the standard of the Codex Alimentarius, proving its poor quality. This work gives value addition to what would normally be regarded as waste by the extraction of oleic acid as a high value product, using the technique of inclusion with urea for the elimination of saturated and unsaturated fatty acids through four successive crystallizations at 4°C and 20°C to have a final phase with oleic acid purity of 95.49%, as a biodegradable soap and a high quality glycerin will be produced by the reaction of saponification and transesterification.

摘要

由于摩洛哥的气候有利于橄榄油生产,其在经济和营养方面具有重要意义,该国的橄榄油产量最近大幅增长。通过压榨或离心提取橄榄油后,所得液体包含油和植物水,随后通过倾析或离心进行分离。尽管在整个提取过程中都进行了处理,但这种橄榄油厂废水(OMW)仍然含有非常重要的油性残留物,一直被视为废弃物。从OMW中分离出的油因其3.397%的高酸度而不能用于食品,该酸度超过了食品法典标准规定的人类消费国际标准,证明其质量较差。这项工作通过将油酸作为高价值产品进行提取,为通常被视为废物的东西赋予了附加值,采用尿素包合法技术,通过在4°C和20°C下连续四次结晶来消除饱和脂肪酸和不饱和脂肪酸,以获得油酸纯度为95.49%的最终产物,同时通过皂化和酯交换反应将生产出可生物降解的肥皂和高质量的甘油。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e0b/4736953/c2e7a6d10654/BMRI2016-1397852.001.jpg

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