Zhong Jinpan, Yuan Zhiqin, Lu Chao
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China.
Anal Bioanal Chem. 2016 Dec;408(30):8731-8746. doi: 10.1007/s00216-016-9449-4. Epub 2016 Mar 12.
Layered nanomaterial has become a popular hierarchical material for amplifying chemiluminescence (CL) in recent years, mainly because of its ease of preparation and modification, large specific surface area, and high catalytic activity. In this review, we mainly discuss layered-nanomaterial-amplified CL systems based on graphene and its derivatives, layered double hydroxides, and clay. Detection mechanisms and strategies of layered-nanomaterial-amplified CL systems are provided to show the basic concepts for designing sensitive and selective sensing systems. Strategies for expanding the applications of layered-nanomaterial-amplified CL systems by combination with surfactants, quantum dots, organic dyes, and nanoparticles are introduced for the analysis of various analytes in real samples. The challenges and future trends of layered-nanomaterial-amplified CL systems are discussed at the end of the review. Graphical Abstract Schematic illustration of layered nanomaterial amplified chemiluminescence.
近年来，层状纳米材料已成为一种用于增强化学发光（CL）的热门分级材料，主要是因为其易于制备和修饰、比表面积大以及催化活性高。在本综述中，我们主要讨论基于石墨烯及其衍生物、层状双氢氧化物和黏土的层状纳米材料增强CL体系。提供了层状纳米材料增强CL体系的检测机制和策略，以展示设计灵敏且选择性传感体系的基本概念。介绍了通过与表面活性剂、量子点、有机染料和纳米颗粒相结合来扩展层状纳米材料增强CL体系应用的策略，用于实际样品中各种分析物的分析。综述结尾讨论了层状纳米材料增强CL体系面临的挑战和未来趋势。图形摘要 层状纳米材料增强化学发光的示意图。
