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通过水溶性聚乙烯醇聚合物方法实现晶圆级化学气相沉积二维原子晶体的无 PMMA 刻蚀转移。

PMMA-Etching-Free Transfer of Wafer-scale Chemical Vapor Deposition Two-dimensional Atomic Crystal by a Water Soluble Polyvinyl Alcohol Polymer Method.

机构信息

Department of Physics and Interdisciplinary Course of Physics and Chemistry, Sungkyunkwan University, 2066, Seobu-Ro, Jangan-Gu, Suwon, Gyeonggi-do 16419, Republic of Korea.

Teraleader Inc., 55-8, Techno-11ro, Yuseong-gu, Daejeon 34036, Republic of Korea.

出版信息

Sci Rep. 2016 Sep 12;6:33096. doi: 10.1038/srep33096.

DOI:10.1038/srep33096
PMID:27616038
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5018882/
Abstract

We have explored a facile technique to transfer large area 2-Dimensional (2D) materials grown by chemical vapor deposition method onto various substrates by adding a water-soluble Polyvinyl Alcohol (PVA) layer between the polymethyl-methacrylate (PMMA) and the 2D material film. This technique not only allows the effective transfer to an arbitrary target substrate with a high degree of freedom, but also avoids PMMA etching thereby maintaining the high quality of the transferred 2D materials with minimum contamination. We applied this method to transfer various 2D materials grown on different rigid substrates of general interest, such as graphene on copper foil, h-BN on platinum and MoS2 on SiO2/Si. This facile transfer technique has great potential for future research towards the application of 2D materials in high performance optical, mechanical and electronic devices.

摘要

我们探索了一种简便的技术,可以通过在聚甲基丙烯酸甲酯(PMMA)和二维材料薄膜之间添加水溶性聚乙烯醇(PVA)层,将通过化学气相沉积法生长的大面积二维(2D)材料转移到各种基底上。这种技术不仅允许在高度自由的情况下将其有效地转移到任意目标基底上,而且还避免了 PMMA 的刻蚀,从而以最小的污染程度保持了转移的二维材料的高质量。我们将这种方法应用于转移在不同刚性基底上生长的各种二维材料,例如铜箔上的石墨烯、铂上的 h-BN 和 SiO2/Si 上的 MoS2。这种简便的转移技术对于未来研究二维材料在高性能光学、机械和电子器件中的应用具有很大的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/e8bcee479de1/srep33096-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/ad53d9bb9fb7/srep33096-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/38245b9ecd13/srep33096-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/439e3a121599/srep33096-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/5aa215fa65cb/srep33096-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/e8bcee479de1/srep33096-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/ad53d9bb9fb7/srep33096-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/38245b9ecd13/srep33096-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/439e3a121599/srep33096-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/5aa215fa65cb/srep33096-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c33f/5018882/e8bcee479de1/srep33096-f5.jpg

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2
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Adv Mater. 2015 Feb 25;27(8):1376-82. doi: 10.1002/adma.201404541. Epub 2014 Dec 18.
3
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9
Plasticized Polystyrene by Addition of -Diene Based Molecules for Defect-Less CVD Graphene Transfer.通过添加基于二烯的分子增塑聚苯乙烯用于无缺陷化学气相沉积石墨烯转移
Polymers (Basel). 2020 Aug 17;12(8):1839. doi: 10.3390/polym12081839.
10
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Nanomaterials (Basel). 2019 Dec 20;10(1):23. doi: 10.3390/nano10010023.
可控生长和单层 MoS2 在 Au 箔上的转移及其在析氢反应中的潜在应用。
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4
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5
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6
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7
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9
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10
Efficient transfer of large-area graphene films onto rigid substrates by hot pressing.热压法高效转移大面积石墨烯薄膜至刚性基底。
ACS Nano. 2012 Jun 26;6(6):5360-5. doi: 10.1021/nn301207d. Epub 2012 Jun 5.