镍-氮修饰石墨烯：一种高效电催化剂，用于将二氧化碳还原为一氧化碳。
Nickel-Nitrogen-Modified Graphene: An Efficient Electrocatalyst for the Reduction of Carbon Dioxide to Carbon Monoxide.
机构信息
Department of Applied Chemistry, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, 560-8531, Japan.
出版信息
Small. 2016 Nov;12(44):6083-6089. doi: 10.1002/smll.201602158. Epub 2016 Sep 16.
Nickel-nitrogen-modified graphene (Ni-N-Gr) is fabricated and Ni-N coordination sites on Ni-N-Gr as active centers effectively reduce CO to CO. The faradaic efficiency for CO formation reaches 90% at -0.7 to -0.9 V versus RHE, and the turnover frequency for CO production comes up to ≈2700 h at -0.7 V versus RHE.
镍-氮修饰石墨烯（Ni-N-Gr）被制备出来，Ni-N-Gr 上的镍-氮配位作为活性中心有效将 CO 还原为 CO。在相对于 RHE 为-0.7 至-0.9 V 的电位下，CO 形成的法拉第效率达到 90%，在相对于 RHE 为-0.7 V 的电位下，CO 生成的周转频率高达 ≈2700 h。
Zotero 插件