通过直接飞秒激光写入制作的丝绸图案。
Silk patterns made by direct femtosecond laser writing.
作者信息
Maximova Ksenia, Wang Xuewen, Balčytis Armandas, Fan Linpeng, Li Jingliang, Juodkazis Saulius
机构信息
Center for Micro-Photonics, Swinburne University of Technology , John St., Hawthorn, Victoria 3122, Australia.
Australian Future Fibers Research and Innovation Centre, Institute for Frontier Materials, Deakin University , Geelong, Victoria 3220, Australia.
出版信息
Biomicrofluidics. 2016 Sep 2;10(5):054101. doi: 10.1063/1.4962294. eCollection 2016 Sep.
Abstract
Silk patterns in a film of amorphous water-soluble fibroin are created by tailored exposure to femtosecond-laser pulses (1030 nm/230 fs) without the use of photo-initiators. This shows that amorphous silk can be used as a negative tone photo-resist. It is also shown that water insoluble crystalline silk films can be precisely ablated from a glass substrate achieving the patterns of crystalline silk gratings on a glass substrate. Bio-compatible/degradable silk can be laser structured to achieve conformational transformations as demonstrated by infrared spectroscopy.
摘要
通过定制飞秒激光脉冲（1030纳米/230飞秒）照射，无需使用光引发剂，即可在非晶态水溶性丝素蛋白薄膜中形成丝图案。这表明非晶态丝可作为负性光刻胶使用。还表明水不溶性结晶丝薄膜可从玻璃基板上精确烧蚀，从而在玻璃基板上实现结晶丝光栅图案。如红外光谱所示，生物相容性/可降解丝可通过激光结构化实现构象转变。
相似文献
1
Silk patterns made by direct femtosecond laser writing.通过直接飞秒激光写入制作的丝绸图案。
Biomicrofluidics. 2016 Sep 2;10(5):054101. doi: 10.1063/1.4962294. eCollection 2016 Sep.
2
Silk Fibroin Degradation Related to Rheological and Mechanical Properties.与流变学和力学性能相关的丝素蛋白降解
Macromol Biosci. 2016 May;16(5):666-75. doi: 10.1002/mabi.201500370. Epub 2016 Jan 12.
3
Biodegradable materials based on silk fibroin and keratin.基于丝素蛋白和角蛋白的可生物降解材料。
Biomacromolecules. 2008 Apr;9(4):1299-305. doi: 10.1021/bm7012789. Epub 2008 Mar 21.
4
Silk I and Silk II studied by fast scanning calorimetry.采用快速扫描量热法研究丝素 I 和丝素 II。
Acta Biomater. 2017 Jun;55:323-332. doi: 10.1016/j.actbio.2017.04.001. Epub 2017 Apr 5.
5
Femtosecond laser direct writing of diffraction grating and its refractive index change in chalcogenide AsSe film.飞秒激光直写硫系化合物AsSe薄膜中的衍射光栅及其折射率变化
Opt Express. 2019 Oct 14;27(21):30090-30101. doi: 10.1364/OE.27.030090.
6
Aqueous multiphoton lithography with multifunctional silk-centred bio-resists.基于多功能丝质中心生物抗蚀剂的水相多光子光刻技术。
Nat Commun. 2015 Oct 16;6:8612. doi: 10.1038/ncomms9612.
7
Femtosecond versus picosecond laser machining of nano-gratings and micro-channels in silica glass.飞秒激光与皮秒激光在石英玻璃中加工纳米光栅和微通道的比较。
Opt Express. 2013 Feb 25;21(4):3946-58. doi: 10.1364/OE.21.003946.
8
Nanoscale Printing of Indium-Tin-Oxide by Femtosecond Laser Pulses.飞秒激光脉冲对氧化铟锡的纳米级打印
Nanomaterials (Basel). 2022 Nov 21;12(22):4092. doi: 10.3390/nano12224092.
9
Insoluble and flexible silk films containing glycerol.含甘油的不溶性和弹性丝膜。
Biomacromolecules. 2010 Jan 11;11(1):143-50. doi: 10.1021/bm900993n.
10
Ultrafast temporal-spatial dynamics of amorphous-to-crystalline phase transition in GeSbTe thin film triggered by multiple femtosecond laser pulses irradiation.多飞秒激光脉冲辐照触发 GeSbTe 薄膜非晶-晶相转变的超快时空动力学。
Nanotechnology. 2020 Mar 13;31(11):115706. doi: 10.1088/1361-6528/ab5a1a. Epub 2019 Nov 21.
引用本文的文献
1
Multi- and Gray-Scale Thermal Lithography of Silk Fibroin as Water-Developable Resist for Micro and Nanofabrication.丝素的多灰度热致相分离水显影光刻用于微纳加工
Adv Sci (Weinh). 2024 Mar;11(12):e2303518. doi: 10.1002/advs.202303518. Epub 2024 Jan 17.
2
Bioinspired silk fibroin materials: From silk building blocks extraction and reconstruction to advanced biomedical applications.仿生丝素蛋白材料：从丝素构建单元的提取与重构到先进的生物医学应用
Mater Today Bio. 2022 Aug 6;16:100381. doi: 10.1016/j.mtbio.2022.100381. eCollection 2022 Dec.
3
Multiphoton Laser Fabrication of Hybrid Photo-Activable Biomaterials.多光子激光制备杂化光激活生物材料
Sensors (Basel). 2021 Sep 1;21(17):5891. doi: 10.3390/s21175891.
4
Fundamentals of Laser-Based Hydrogel Degradation and Applications in Cell and Tissue Engineering.基于激光的水凝胶降解基础及其在细胞和组织工程中的应用。
Adv Healthc Mater. 2017 Dec;6(24). doi: 10.1002/adhm.201700681. Epub 2017 Oct 24.
5
Orientational Mapping Augmented Sub-Wavelength Hyper-Spectral Imaging of Silk.取向映射增强的丝绸亚波长超光谱成像。
Sci Rep. 2017 Aug 7;7(1):7419. doi: 10.1038/s41598-017-07502-3.
6
Silk: Optical Properties over 12.6 Octaves THz-IR-Visible-UV Range.丝绸：12.6个倍频程太赫兹-红外-可见光-紫外波段的光学特性
Materials (Basel). 2017 Mar 28;10(4):356. doi: 10.3390/ma10040356.
7
Optically Clear and Resilient Free-Form µ-Optics 3D-Printed via Ultrafast Laser Lithography.通过超快激光光刻3D打印的光学透明且有弹性的自由形式微光学器件
Materials (Basel). 2017 Jan 2;10(1):12. doi: 10.3390/ma10010012.
本文引用的文献
1
Ultrafast laser processing of materials: from science to industry.材料的超快激光加工：从科学到工业
Light Sci Appl. 2016 Aug 12;5(8):e16133. doi: 10.1038/lsa.2016.133. eCollection 2016 Aug.
2
Aqueous multiphoton lithography with multifunctional silk-centred bio-resists.基于多功能丝质中心生物抗蚀剂的水相多光子光刻技术。
Nat Commun. 2015 Oct 16;6:8612. doi: 10.1038/ncomms9612.
3
Identification and classification of silks using infrared spectroscopy.利用红外光谱法对丝绸进行鉴定和分类。
J Exp Biol. 2015 Oct;218(Pt 19):3138-49. doi: 10.1242/jeb.128306. Epub 2015 Sep 7.
4
Silk-based biomaterials in biomedical textiles and fiber-based implants.生物医学纺织品和纤维基植入物中的丝基生物材料。
Adv Healthc Mater. 2015 Jun 3;4(8):1134-51. doi: 10.1002/adhm.201500002. Epub 2015 Mar 13.
5
All-water-based electron-beam lithography using silk as a resist.使用丝作为抗蚀剂的全水基电子束光刻技术。
Nat Nanotechnol. 2014 Apr;9(4):306-10. doi: 10.1038/nnano.2014.47. Epub 2014 Mar 23.
6
Three-dimensional laser micro-sculpturing of silicone: towards bio-compatible scaffolds.硅酮的三维激光微雕刻：迈向生物相容性支架
Opt Express. 2013 Jul 15;21(14):17028-41. doi: 10.1364/OE.21.017028.
7
Additional enhancement of electric field in surface-enhanced Raman Scattering due to Fresnel mechanism.菲涅耳机制导致的表面增强拉曼散射中电场的额外增强。
Sci Rep. 2013;3:2335. doi: 10.1038/srep02335.
8
Insight into the structure of single Antheraea pernyi silkworm fibers using synchrotron FTIR microspectroscopy.利用同步辐射傅里叶变换红外显微镜技术研究单个柞蚕丝纤维的结构。
Biomacromolecules. 2013 Jun 10;14(6):1885-92. doi: 10.1021/bm400267m. Epub 2013 May 3.
9
Black silicon: substrate for laser 3D micro/nano-polymerization.黑色硅：用于激光3D微纳聚合的基底。
Opt Express. 2013 Mar 25;21(6):6901-9. doi: 10.1364/OE.21.006901.
10
Beating the heat--fast scanning melts silk beta sheet crystals.抗热——快速扫描使丝素β 片晶熔融。
Sci Rep. 2013;3:1130. doi: 10.1038/srep01130. Epub 2013 Jan 24.
Zotero 插件