School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China.
College of Environmental Science and Engineering, Beijing Forestry University, Beijing, 100083, China.
Environ Sci Pollut Res Int. 2017 Jan;24(2):1251-1260. doi: 10.1007/s11356-016-7849-9. Epub 2016 Oct 22.
A promising Li-rich high-capacity cathode material (xLiMnO·(1-x)LiMnNiO) has received much attention with regard to improving the performance of lithium-ion batteries in electric vehicles. This study presents an environmental impact evaluation of a lithium-ion battery with Li-rich materials used in an electric vehicle throughout the life cycle of the battery. A comparison between this cathode material and a Li-ion cathode material containing cobalt was compiled in this study. The battery use stage was found to play a large role in the total environmental impact and high greenhouse gas emissions. During battery production, cathode material manufacturing has the highest environmental impact due to its complex processing and variety of raw materials. Compared to the cathode with cobalt, the Li-rich material generates fewer impacts in terms of human health and ecosystem quality. Through the life cycle assessment (LCA) results and sensitivity analysis, we found that the electricity mix and energy efficiency significantly influence the environmental impacts of both battery production and battery use. This paper also provides a detailed life cycle inventory, including firsthand data on lithium-ion batteries with Li-rich cathode materials.
一种有前景的富锂高容量正极材料(xLiMnO·(1-x)LiMnNiO),在提高电动汽车锂离子电池的性能方面受到了广泛关注。本研究对富锂材料在电动汽车锂离子电池的整个生命周期内的环境影响进行了评价。本研究对这种正极材料与含钴的锂离子正极材料进行了比较。研究发现,在总环境影响和温室气体排放方面,电池使用阶段起着重要作用。在电池生产过程中,由于其复杂的加工工艺和多种原材料,正极材料的制造对环境的影响最大。与含钴的正极相比,富锂材料在人体健康和生态质量方面的影响较小。通过生命周期评估(LCA)结果和敏感性分析,我们发现电力组合和能源效率显著影响电池生产和电池使用的环境影响。本文还提供了详细的生命周期清单,包括富锂正极材料锂离子电池的第一手数据。