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Concerted nucleophilic aromatic substitutions.
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3
Isotope effects and the mechanism of an electron-transfer-catalyzed Diels-Alder reaction.
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Impact of kinetic isotope effects in isotopic studies of metabolic systems.
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Determining Carbon Kinetic Isotope Effects Using Headspace Analysis of Evolved CO.
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Stereoselective Approaches to β-Linked 2-Deoxy Sugars.
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Dual-Hydrogen-Bond Donor and Brønsted Acid Cocatalysis Enables Highly Enantioselective Protio-Semipinacol Rearrangement Reactions.
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Mimicry of the proton wire mechanism of enzymes inside a supramolecular capsule enables β-selective O-glycosylations.
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Glycosyl Sulfonates Beyond Triflates.
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En Route to the Transformation of Glycoscience: A Chemist's Perspective on Internal and External Crossroads in Glycochemistry.
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Enantioselective Aryl-Iodide-Catalyzed Wagner-Meerwein Rearrangements.
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Macrocyclic bis-thioureas catalyze stereospecific glycosylation reactions.
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Transition state analysis of enantioselective Brønsted base catalysis by chiral cyclopropenimines.
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A general approach to mechanism in multiproduct reactions: product-specific intermolecular kinetic isotope effects.
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Highly precise measurement of kinetic isotope effects using 1H-detected 2D [13C,1H]-HSQC NMR spectroscopy.
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Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydes.
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Measurements of heavy-atom isotope effects using 1H NMR spectroscopy.
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Mechanism of a chemical glycosylation reaction.
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A direct NMR method for the measurement of competitive kinetic isotope effects.
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Quantitative (13)C NMR spectroscopy using refocused constant-time INEPT, Q-INEPT-CT.
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