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一种具有高锂离子电导率、机械强度和柔韧性的人工固态电解质中间相,用于稳定的锂金属阳极。

An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes.

机构信息

Department of Materials Science and Engineering, Stanford University, Stanford, CA, 94305, USA.

Department of Mechanical Engineering, Stanford University, Stanford, CA, 94305, USA.

出版信息

Adv Mater. 2017 Mar;29(10). doi: 10.1002/adma.201605531. Epub 2016 Dec 29.

DOI:10.1002/adma.201605531
PMID:28032934
Abstract

An artificial solid electrolyte interphase (SEI) is demonstrated for the efficient and safe operation of a lithium metal anode. Composed of lithium-ion-conducting inorganic nanoparticles within a flexible polymer binder matrix, the rationally designed artificial SEI not only mechanically suppresses lithium dendrite formation but also promotes homogeneous lithium-ion flux, significantly enhancing the efficiency and cycle life of the lithium metal anode.

摘要

一种人工固体电解质界面(SEI)被证明可有效且安全地用于锂金属阳极的工作。该人工 SEI 由可传导锂离子的无机纳米粒子与柔性聚合物粘结剂基质组成,其合理设计不仅可机械抑制锂枝晶的形成,还可促进锂离子的均匀通量,从而显著提高锂金属阳极的效率和循环寿命。

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