Rit Raja K, Shankar Majji, Sahoo Akhila K
School of Chemistry, University of Hyderabad, Hyderabad, Prof. C R Rao Road, Gachibowli, Telangana 500046, India.
Org Biomol Chem. 2017 Feb 7;15(6):1282-1293. doi: 10.1039/c6ob02162j.
The direct imidation strategy proficiently constructs C-N bonds and creates the useful amine functional group in the molecular template. This review briefly discusses the synthetic methods developed for the direct imidation of unactivated C(sp/sp/sp)-H bonds. Transition-metal catalysts, metal-free processes, and/or photo-induced methods are invariably employed for accomplishing C-H imidation transformations. The contents summarized herein would benefit the research community to use the C-H imidation reactions for broad synthetic applications and to unravel novel C-N bond forming processes.
直接亚胺化策略能够高效地构建C-N键，并在分子模板中引入有用的胺官能团。本文简要讨论了为未活化的C(sp³/sp²/sp) -H键直接亚胺化所开发的合成方法。过渡金属催化剂、无金属过程和/或光诱导方法常用于实现C-H亚胺化转化。本文总结的内容将有助于研究团体将C-H亚胺化反应用于广泛的合成应用，并揭示新型C-N键形成过程。
