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环境因素和基质在丁基锡吸附、解吸及毒性方面的重要性:综述

The importance of environmental factors and matrices in the adsorption, desorption, and toxicity of butyltins: a review.

作者信息

Fang Liping, Xu Cuihong, Li Ji, Borggaard Ole K, Wang Dongsheng

机构信息

Department of Chemistry, Faculty of Material Sciences and Chemistry, China University of Geosciences, Wuhan, 430074, China.

Department of Plant and Environmental Sciences, University of Copenhagen, Thorvaldsensvej 40, DK-1871, Frederiksberg C, Denmark.

出版信息

Environ Sci Pollut Res Int. 2017 Apr;24(10):9159-9173. doi: 10.1007/s11356-017-8449-z. Epub 2017 Feb 4.

Abstract

Butyltins (BTs) are considered as a group of the most important organometallic compounds in industry and agriculture. Due to their widespread use, large amounts of BTs including tributyltin (TBT), dibutyltin (DBT), and monobutyltin (MBT) have entered into the environment, and subsequently causing detrimental effects on humans and aquatic organisms. This work provides a critical review of recent studies on the adsorption, desorption, bioaccumulation, and toxicity of BTs that can notably influence the distribution of BTs in the environment. Influence of environmental factors (e.g., pH and salinity) and adsorbents in the matrices (e.g., minerals, organic carbons, and quartz) on the adsorption, desorption, and toxicity of BTs is particularly addressed.

摘要

丁基锡化合物(BTs)被认为是工农业中最重要的一类有机金属化合物。由于其广泛使用,大量的丁基锡化合物,包括三丁基锡(TBT)、二丁基锡(DBT)和单丁基锡(MBT)进入环境,随后对人类和水生生物造成有害影响。这项工作对近期关于丁基锡化合物吸附、解吸、生物累积和毒性的研究进行了批判性综述,这些研究显著影响丁基锡化合物在环境中的分布。特别讨论了环境因素(如pH值和盐度)以及基质中的吸附剂(如矿物质、有机碳和石英)对丁基锡化合物吸附、解吸和毒性的影响。

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