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X 射线布拉格光顺术在单个 InGaN/GaN 核壳纳米线上的应用。

X-ray Bragg Ptychography on a Single InGaN/GaN Core-Shell Nanowire.

机构信息

Deutsches Elektronen-Synchrotron DESY , Notkestraße 85, D-22607 Hamburg, Germany.

Niels Bohr Institute, University of Copenhagen , Blegdamsvej 17, 2100 Copenhagen, Denmark.

出版信息

ACS Nano. 2017 Jul 25;11(7):6605-6611. doi: 10.1021/acsnano.6b08122. Epub 2017 Mar 20.

Abstract

The future of solid-state lighting can be potentially driven by applications of InGaN/GaN core-shell nanowires. These heterostructures provide the possibility for fine-tuning of functional properties by controlling a strain state between mismatched layers. We present a nondestructive study of a single 400 nm-thick InGaN/GaN core-shell nanowire using two-dimensional (2D) X-ray Bragg ptychography (XBP) with a nanofocused X-ray beam. The XBP reconstruction enabled the determination of a detailed three-dimensional (3D) distribution of the strain in the particular nanowire using a model based on finite element method. We observed the strain induced by the lattice mismatch between the GaN core and InGaN shell to be in the range from -0.1% to 0.15% for an In concentration of 30%. The maximum value of the strain component normal to the facets was concentrated at the transition region between the main part of the nanowire and the GaN tip. In addition, a variation in misfit strain relaxation between the axial growth and in-plane directions was revealed.

摘要

未来的固态照明可能会受到 InGaN/GaN 核壳纳米线的应用驱动。这些异质结构通过控制不匹配层之间的应变状态,为精细调整功能特性提供了可能性。我们使用纳米聚焦 X 射线束的二维(2D)X 射线布拉格光顺(XBP)对单个 400nm 厚的 InGaN/GaN 核壳纳米线进行了无损研究。XBP 重建使我们能够使用基于有限元方法的模型确定特定纳米线中应变的详细三维(3D)分布。我们观察到,对于 30%的 In 浓度,GaN 核和 InGaN 壳之间的晶格失配对应变的影响范围在-0.1%到 0.15%之间。垂直于晶面的应变分量的最大值集中在纳米线的主体部分和 GaN 尖端之间的过渡区域。此外,还揭示了轴向生长和平面方向之间的失配应变松弛的变化。

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