Kim Sung-Un, Ra Yong-Ho
Optic & Electronic Component Material Center, Korea Institute of Ceramic Engineering & Technology, Jinju 52851, Korea.
Division of Materials Science and Engineering, Hanyang University, 222, Wangsimni-ro, Seongdong-gu, Seoul 04763, Korea.
Nanomaterials (Basel). 2020 Dec 23;11(1):9. doi: 10.3390/nano11010009.
One-dimensional nanowires based on Group III-nitride materials are emerging as one of the most promising structures for applications of light-emitting diodes (LEDs), laser diodes (LDs), solar cells, and photocatalysts. However, leading to the so-called "green gap" in photonics, the fabrication of high concentration indium gallium nitride (InGaN) and -InGaN structures remains still challenging. In this study, we performed simulations for structural modeling of uniform temperature distribution in a nanowire epitaxy, and have successfully developed high-concentration InGaN and -InGaN nanowire heterostructures on silicon (Si) substrate using molecular beam epitaxy (MBE) system. From scanning electron microscope (SEM) and transmission electron microscope (TEM) results, it was confirmed that the various doped-InGaN nanowire structures show much higher crystal quality compared to conventional nanowire structures. By introducing a new three-step modulated growth technique, the -/-InGaN active regions were greatly increased and the optical properties were also dramatically improved due to reduced phase separation. In addition, a multi-band -InGaN/GaN heterostructure was successfully fabricated with the core-shell nanowire structures, which enable the emission of light in the entire visible spectral range, and protect the InGaN surface from surface recombination. This paper offers important insight into the design and epitaxial growth of InGaN nanowire heterostructures.
基于III族氮化物材料的一维纳米线正成为发光二极管(LED)、激光二极管(LD)、太阳能电池和光催化剂应用中最具潜力的结构之一。然而,由于光子学中存在所谓的“绿色差距”,高浓度氮化铟镓(InGaN)和-InGaN结构的制造仍然具有挑战性。在本研究中,我们对纳米线外延中均匀温度分布的结构建模进行了模拟,并使用分子束外延(MBE)系统在硅(Si)衬底上成功开发了高浓度InGaN和-InGaN纳米线异质结构。从扫描电子显微镜(SEM)和透射电子显微镜(TEM)的结果可以确认,与传统纳米线结构相比,各种掺杂InGaN纳米线结构具有更高的晶体质量。通过引入一种新的三步调制生长技术,由于相分离减少,-/-InGaN有源区大大增加,光学性能也得到显著改善。此外,成功制备了具有核壳纳米线结构的多波段-InGaN/GaN异质结构,该结构能够在整个可见光谱范围内发光,并保护InGaN表面免受表面复合的影响。本文为InGaN纳米线异质结构的设计和外延生长提供了重要的见解。