Institute of Materials and Systems for Sustainability (IMaSS), Nagoya University, Nagoya, 464-8603, Japan.
School of Electrical Engineering and Computer Science, Gwangju Institute of Science and Technology (GIST), Gwangju, 61005, Republic of Korea.
Sci Rep. 2017 Mar 27;7:45345. doi: 10.1038/srep45345.
We report the fabrication of near-vertically elongated GaN nanorods on quartz substrates. To control the preferred orientation and length of individual GaN nanorods, we combined molecular beam epitaxy (MBE) with pulsed-mode metal-organic chemical vapor deposition (MOCVD). The MBE-grown buffer layer was composed of GaN nanograins exhibiting an ordered surface and preferred orientation along the surface normal direction. Position-controlled growth of the GaN nanorods was achieved by selective-area growth using MOCVD. Simultaneously, the GaN nanorods were elongated by the pulsed-mode growth. The microstructural and optical properties of both GaN nanorods and InGaN/GaN core-shell nanorods were then investigated. The nanorods were highly crystalline and the core-shell structures exhibited optical emission properties, indicating the feasibility of fabricating III-nitride nano-optoelectronic devices on amorphous substrates.
我们报告了在石英衬底上制备近垂直伸长 GaN 纳米棒。为了控制单个 GaN 纳米棒的择优取向和长度,我们将分子束外延(MBE)与脉冲式金属有机化学气相沉积(MOCVD)相结合。MBE 生长的缓冲层由 GaN 纳米颗粒组成,这些纳米颗粒具有有序的表面和沿表面法线方向的择优取向。通过使用 MOCVD 进行选择性区域生长,可以实现 GaN 纳米棒的位置控制生长。同时,脉冲式生长使 GaN 纳米棒伸长。然后研究了 GaN 纳米棒和 InGaN/GaN 核壳纳米棒的微结构和光学性质。纳米棒具有高结晶性,核壳结构表现出光学发射性质,表明在非晶衬底上制造 III 族氮化物纳米光电设备是可行的。