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用于高性能钙钛矿太阳能电池的TiO纳米纤维光电极中的碳纳米管

Carbon Nanotubes in TiO Nanofiber Photoelectrodes for High-Performance Perovskite Solar Cells.

作者信息

Batmunkh Munkhbayar, Macdonald Thomas J, Shearer Cameron J, Bat-Erdene Munkhjargal, Wang Yun, Biggs Mark J, Parkin Ivan P, Nann Thomas, Shapter Joseph G

机构信息

School of Chemical Engineering The University of Adelaide Adelaide South Australia 5005 Australia.

School of Chemical and Physical Sciences Flinders University Bedford Park, Adelaide South Australia 5042 Australia.

出版信息

Adv Sci (Weinh). 2017 Jan 20;4(4):1600504. doi: 10.1002/advs.201600504. eCollection 2017 Apr.

DOI:10.1002/advs.201600504
PMID:28435781
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5396161/
Abstract

1D semiconducting oxides are unique structures that have been widely used for photovoltaic (PV) devices due to their capability to provide a direct pathway for charge transport. In addition, carbon nanotubes (CNTs) have played multifunctional roles in a range of PV cells because of their fascinating properties. Herein, the influence of CNTs on the PV performance of 1D titanium dioxide nanofiber (TiO NF) photoelectrode perovskite solar cells (PSCs) is systematically explored. Among the different types of CNTs, single-walled CNTs (SWCNTs) incorporated in the TiO NF photoelectrode PSCs show a significant enhancement (≈40%) in the power conversion efficiency (PCE) as compared to control cells. SWCNTs incorporated in TiO NFs provide a fast electron transfer within the photoelectrode, resulting in an increase in the short-circuit current () value. On the basis of our theoretical calculations, the improved open-circuit voltage () of the cells can be attributed to a shift in energy level of the photoelectrodes after the introduction of SWCNTs. Furthermore, it is found that the incorporation of SWCNTs into TiO NFs reduces the hysteresis effect and improves the stability of the PSC devices. In this study, the best performing PSC device constructed with SWCNT structures achieves a PCE of 14.03%.

摘要

一维半导体氧化物是独特的结构，由于其能够为电荷传输提供直接路径，已被广泛用于光伏（PV）器件。此外，碳纳米管（CNT）因其迷人的特性，在一系列光伏电池中发挥了多功能作用。在此，系统地探究了碳纳米管对一维二氧化钛纳米纤维（TiO NF）光电极钙钛矿太阳能电池（PSC）光伏性能的影响。在不同类型的碳纳米管中，与对照电池相比，掺入TiO NF光电极PSC中的单壁碳纳米管（SWCNT）在功率转换效率（PCE）方面显示出显著提高（约40%）。掺入TiO NF中的SWCNT在光电极内提供快速电子转移，导致短路电流（）值增加。基于我们的理论计算，电池开路电压（）的提高可归因于引入SWCNT后光电极能级的变化。此外，发现将SWCNT掺入TiO NF中可降低滞后效应并提高PSC器件的稳定性。在本研究中，采用SWCNT结构构建的性能最佳的PSC器件实现了14.03%的PCE。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/fd57d9900bd3/ADVS-4-na-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/d33864dcc7d6/ADVS-4-na-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/7ab30de8d0de/ADVS-4-na-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/78db06953ba4/ADVS-4-na-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/0720669fdf26/ADVS-4-na-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/fd57d9900bd3/ADVS-4-na-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/d33864dcc7d6/ADVS-4-na-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/5d2d6bb3b480/ADVS-4-na-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/31b4351cf586/ADVS-4-na-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/e9466a2b491a/ADVS-4-na-g005.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/78db06953ba4/ADVS-4-na-g007.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/779b/5396161/fd57d9900bd3/ADVS-4-na-g009.jpg

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本文引用的文献

1
NiO Nanofibers as a Candidate for a Nanophotocathode.氧化镍纳米纤维作为纳米光阴极的候选材料。
Nanomaterials (Basel). 2014 Apr 3;4(2):256-266. doi: 10.3390/nano4020256.
2
Carbonaceous Dye-Sensitized Solar Cell Photoelectrodes.碳质染料敏化太阳能电池光电极
Adv Sci (Weinh). 2015 Feb 18;2(3):1400025. doi: 10.1002/advs.201400025. eCollection 2015 Mar.
3
High Performance Perovskite Solar Cells.高性能钙钛矿太阳能电池。
使用源自储量丰富的天然石墨的还原氧化石墨烯提高钙钛矿太阳能电池的效率和稳定性
RSC Adv. 2020 Mar 3;10(15):9133-9139. doi: 10.1039/d0ra01423k. eCollection 2020 Feb 27.
4
Surface Treatment of Cu:NiOx Hole-Transporting Layer Using β-Alanine for Hysteresis-Free and Thermally Stable Inverted Perovskite Solar Cells.使用β-丙氨酸对Cu:NiOx空穴传输层进行表面处理以制备无滞后且热稳定的倒置钙钛矿太阳能电池
Nanomaterials (Basel). 2020 Oct 1;10(10):1961. doi: 10.3390/nano10101961.
5
Au-Embedded and Carbon-Doped Freestanding TiO Nanotube Arrays in Dye-Sensitized Solar Cells for Better Energy Conversion Efficiency.用于提高能量转换效率的染料敏化太阳能电池中的金嵌入和碳掺杂独立式二氧化钛纳米管阵列
Micromachines (Basel). 2019 Nov 22;10(12):805. doi: 10.3390/mi10120805.
6
Electrically Sorted Single-Walled Carbon Nanotubes-Based Electron Transporting Layers for Perovskite Solar Cells.用于钙钛矿太阳能电池的基于电分类单壁碳纳米管的电子传输层
iScience. 2019 Apr 26;14:100-112. doi: 10.1016/j.isci.2019.03.015. Epub 2019 Mar 20.
7
Enhanced Silver Nanowire Composite Window Electrode Protected by Large Size Graphene Oxide Sheets for Perovskite Solar Cells.用于钙钛矿太阳能电池的由大尺寸氧化石墨烯片保护的增强型银纳米线复合窗口电极
Nanomaterials (Basel). 2019 Feb 2;9(2):193. doi: 10.3390/nano9020193.
8
Interface Passivation Effects on the Photovoltaic Performance of Quantum Dot Sensitized Inverse Opal TiO₂ Solar Cells.界面钝化对量子点敏化反蛋白石TiO₂太阳能电池光伏性能的影响
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9
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10
Optical fiber ultrasound transmitter with electrospun carbon nanotube-polymer composite.具有电纺碳纳米管-聚合物复合材料的光纤超声发射器。
Appl Phys Lett. 2017 May 29;110(22):223701. doi: 10.1063/1.4984838. Epub 2017 Jun 1.
Adv Sci (Weinh). 2015 Dec 2;3(5):1500201. doi: 10.1002/advs.201500201. eCollection 2016 May.
4
Photovoltaic materials: Present efficiencies and future challenges.光伏材料：当前效率与未来挑战。
Science. 2016 Apr 15;352(6283):aad4424. doi: 10.1126/science.aad4424.
5
Fiber-Shaped Perovskite Solar Cells with High Power Conversion Efficiency.纤维状钙钛矿太阳能电池，具有高光能量转换效率。
Small. 2016 May;12(18):2419-24. doi: 10.1002/smll.201600326. Epub 2016 Mar 22.
6
Enhanced Charge Collection with Passivation Layers in Perovskite Solar Cells.钙钛矿太阳能电池中的钝化层增强电荷收集。
Adv Mater. 2016 May;28(20):3966-72. doi: 10.1002/adma.201505140. Epub 2016 Mar 1.
7
Perovskite Photovoltaics with Outstanding Performance Produced by Chemical Conversion of Bilayer Mesostructured Lead Halide/TiO2 Films.通过双层介孔卤化铅/二氧化钛薄膜的化学转化制备具有优异性能的钙钛矿型光伏器件。
Adv Mater. 2016 Apr 20;28(15):2964-70. doi: 10.1002/adma.201506049. Epub 2016 Feb 19.
8
Origin of J-V Hysteresis in Perovskite Solar Cells.钙钛矿太阳能电池中J-V滞后现象的起源
J Phys Chem Lett. 2016 Mar 3;7(5):905-17. doi: 10.1021/acs.jpclett.6b00215. Epub 2016 Feb 24.
9
Modeling Anomalous Hysteresis in Perovskite Solar Cells.钙钛矿太阳能电池中异常滞后现象的建模
J Phys Chem Lett. 2015 Oct 1;6(19):3808-14. doi: 10.1021/acs.jpclett.5b01645. Epub 2015 Sep 10.
10
Self-Position of Au NPs in Perovskite Solar Cells: Optical and Electrical Contribution.钙钛矿太阳能电池中自定位金纳米颗粒的光学和电学贡献
ACS Appl Mater Interfaces. 2016 Jan 13;8(1):449-54. doi: 10.1021/acsami.5b09365. Epub 2015 Dec 23.