Menezes Prashanth W, Indra Arindam, Gutkin Vitaly, Driess Matthias
Department of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, D-10623 Berlin, Germany. matthias.driess@.tu-berlin.de.
Chem Commun (Camb). 2017 Jul 13;53(57):8018-8021. doi: 10.1039/c7cc03749j.
The strikingly high catalytic performance and stability of manganese substituted cobalt oxide spinel (MnCoO) over pristine cobalt oxide spinel (CoO) for the alkaline electrochemical water oxidation is reported. The different role of cations could be uncovered along with the detection of drastic surface-structural changes during the catalysis using spectroscopic and microscopic methods.
据报道，与原始钴氧化物尖晶石（CoO）相比，锰取代的钴氧化物尖晶石（MnCoO）在碱性电化学水氧化反应中具有显著更高的催化性能和稳定性。利用光谱和显微镜方法，在催化过程中检测到剧烈的表面结构变化，同时也揭示了阳离子的不同作用。
