通过用锰取代氧化钴尖晶石中的O Co位点来促进电化学水氧化。
Boosting electrochemical water oxidation through replacement of O Co sites in cobalt oxide spinel with manganese.
作者信息
Menezes Prashanth W, Indra Arindam, Gutkin Vitaly, Driess Matthias
机构信息
Department of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, D-10623 Berlin, Germany. matthias.driess@.tu-berlin.de.
出版信息
Chem Commun (Camb). 2017 Jul 13;53(57):8018-8021. doi: 10.1039/c7cc03749j.
The strikingly high catalytic performance and stability of manganese substituted cobalt oxide spinel (MnCoO) over pristine cobalt oxide spinel (CoO) for the alkaline electrochemical water oxidation is reported. The different role of cations could be uncovered along with the detection of drastic surface-structural changes during the catalysis using spectroscopic and microscopic methods.
据报道，与原始钴氧化物尖晶石（CoO）相比，锰取代的钴氧化物尖晶石（MnCoO）在碱性电化学水氧化反应中具有显著更高的催化性能和稳定性。利用光谱和显微镜方法，在催化过程中检测到剧烈的表面结构变化，同时也揭示了阳离子的不同作用。
Zotero 插件