Rubio-Cervilla Jon, González Edurne, Pomposo José A
Centro de Física de Materiales (CSIC, UPV/EHU)-MPC, Materials Physics Center, Paseo Manuel de Lardizabal 5, E-20018 San Sebastian, Spain.
Departamento de Física de Materiales, Universidad del País Vasco (UPV/EHU), Apartado 1072, E-20080 San Sebastian, Spain.
Nanomaterials (Basel). 2017 Oct 21;7(10):341. doi: 10.3390/nano7100341.
Enzymes are the most efficient catalysts known for working in an aqueous environment near room temperature. The folding of individual polymer chains to functional single-chain nanoparticles (SCNPs) offers many opportunities for the development of artificial enzyme-mimic catalysts showing both high catalytic activity and specificity. In this review, we highlight recent results obtained in the use of SCNPs as bioinspired, highly-efficient nanoreactors (3-30 nm) for the synthesis of a variety of nanomaterials (inorganic nanoparticles, quantum dots, carbon nanodots), polymers, and chemical compounds, as well as nanocontainers for CO₂ capture and release.
酶是已知在接近室温的水性环境中工作的最有效的催化剂。单个聚合物链折叠成功能性单链纳米颗粒(SCNP)为开发具有高催化活性和特异性的人工酶模拟催化剂提供了许多机会。在这篇综述中,我们重点介绍了使用SCNP作为受生物启发的高效纳米反应器(3-30纳米)来合成各种纳米材料(无机纳米颗粒、量子点、碳纳米点)、聚合物和化合物,以及用于捕获和释放二氧化碳的纳米容器方面取得的最新成果。