钯催化的通过电化学实现的C-H活化/C-C交叉偶联反应
Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistry.
作者信息
Ma Cong, Zhao Chuan-Qi, Li Yi-Qian, Zhang Li-Pu, Xu Xue-Tao, Zhang Kun, Mei Tian-Sheng
机构信息
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China.
出版信息
Chem Commun (Camb). 2017 Nov 9;53(90):12189-12192. doi: 10.1039/c7cc07429h.
Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation.
钯催化的C-H活化/C-C交叉偶联反应通常需要化学计量的化学氧化剂和外源性配体。然而，使用传统的化学计量氧化剂存在显著缺点。为克服这些问题，我们开发了一种电化学策略来实现甲基化和酰化。
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