Nohara Toshihiro, Ono Masateru, Nishioka Naho, Masuda Fuka, Fujiwara Yukio, Ikeda Tsuyoshi, Nakano Daisuke, Kinjo Junei
Faculty of Pharmaceutical Sciences, Sojo University, 4-22-2 Ikeda, Nishi-ku, Kumamoto, 860-0082, Japan.
School of Agriculture, Tokai University, 5435 Minamiaso, Aso, Kumamoto, 869-1404, Japan.
J Nat Med. 2018 Jan;72(1):326-331. doi: 10.1007/s11418-017-1133-2. Epub 2017 Oct 30.
One atypical thiolane-type sulfide, garlicnin I (1), two 3,4-dimethylthiolane-type sulfides, garlicnins M (2) and N (3), and one thiabicyclic-type sulfide, garlicnin O (4), were isolated from the acetone extracts of Chinese garlic bulbs, Allium sativum and their structures were characterized. Hypothetical pathways for the production of the respective sulfides were discussed.
从中国大蒜（蒜）的丙酮提取物中分离出一种非典型的硫杂环戊烷型硫化物大蒜素I（1）、两种3,4-二甲基硫杂环戊烷型硫化物大蒜素M（2）和N（3）以及一种硫双环型硫化物大蒜素O（4），并对其结构进行了表征。讨论了各自硫化物产生的假设途径。
