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Intramolecular Acetyl Transfer to Olefins by Catalytic C-C Bond Activation of Unstrained Ketones.
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2
Rhodium catalyzed 1,4-conjugate addition of 1,5-azastibocines with electron deficient olefins.
Chem Pharm Bull (Tokyo). 2008 Oct;56(10):1502-4. doi: 10.1248/cpb.56.1502.
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Highly enantioselective rhodium(I)-catalyzed carbonyl carboacylations initiated by C-C bond activation.
Angew Chem Int Ed Engl. 2014 Sep 1;53(36):9640-4. doi: 10.1002/anie.201405834. Epub 2014 Jul 14.
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Directing Group-Free Formal Suzuki-Miyaura Coupling of Simple Ketones Enabled by Activation of Unstrained C-C Bonds.
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Skeletal Modification via Activation of Relatively Unstrained C-C Bonds.
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Nickel-Catalyzed Three-Component 1,2-Carboacylation of Alkenes.
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Photoredox cooperative N-heterocyclic carbene/palladium-catalysed alkylacylation of alkenes.
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Rapid syntheses of N-fused heterocycles via acyl-transfer in heteroaryl ketones.
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Temporary or removable directing groups enable activation of unstrained C-C bonds.
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Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C-COCl Bond Cleavage*.
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Two-Carbon Ring Expansion of 1-Indanones via Insertion of Ethylene into Carbon-Carbon Bonds.
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Direct activation of relatively unstrained carbon-carbon bonds in homogeneous systems.
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Nickel-Mediated Decarbonylation of Simple Unstrained Ketones through the Cleavage of Carbon-Carbon Bonds.
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Recent Methodologies That Exploit C-C Single-Bond Cleavage of Strained Ring Systems by Transition Metal Complexes.
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