Pollard Victoria A, Orr Samantha A, McLellan Ross, Kennedy Alan R, Hevia Eva, Mulvey Robert E
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, UK.
Chem Commun (Camb). 2018 Jan 31;54(10):1233-1236. doi: 10.1039/c7cc08214b.
Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.
锂和铝中心之间的协同作用涉及通过杂配二氨基二氢铝酸锂实现醛和酮与频哪醇硼烷的催化硼氢化反应。除了进行氢化铝化反应外，这些多功能杂配酸酯还可以作为酰胺碱，如酸性三唑所示。
