Department of Material Science and Engineering and NUANCE Center, Northwestern University , Evanston, Illinois 60208, United States.
Applied NanoStructures, Inc. , 415 Clyde Ave., Mountain View, California 94043, United States.
ACS Nano. 2018 Feb 27;12(2):1760-1767. doi: 10.1021/acsnano.7b08504. Epub 2018 Feb 9.
The lateral resolution of scanning thermal microscopy (SThM) has hitherto never approached that of mainstream atomic force microscopy, mainly due to poor performance of the thermal sensor. Herein, we report a nanomechanical system-based thermal sensor (thermocouple) that enables high lateral resolution that is often required in nanoscale thermal characterization in a wide range of applications. This thermocouple-based probe technology delivers excellent lateral resolution (∼20 nm), extended high-temperature measurements >700 °C without cantilever bending, and thermal sensitivity (∼0.04 °C). The origin of significantly improved figures-of-merit lies in the probe design that consists of a hollow silicon tip integrated with a vertically oriented thermocouple sensor at the apex (low thermal mass) which interacts with the sample through a metallic nanowire (50 nm diameter), thereby achieving high lateral resolution. The efficacy of this approach to SThM is demonstrated by imaging embedded metallic nanostructures in silica core-shell, metal nanostructures coated with polymer films, and metal-polymer interconnect structures. The nanoscale pitch and extremely small thermal mass of the probe promise significant improvements over existing methods and wide range of applications in several fields including semiconductor industry, biomedical imaging, and data storage.
扫描热显微镜(SThM)的横向分辨率迄今为止从未接近主流原子力显微镜的水平,主要是由于热传感器的性能较差。在此,我们报告了一种基于纳米力学系统的热传感器(热电偶),它能够在广泛的应用中实现纳米级热特性所需的高横向分辨率。这种基于热电偶的探头技术具有出色的横向分辨率(约 20nm)、扩展的高温测量(>700°C,无需悬臂梁弯曲)和热灵敏度(约 0.04°C)。显著提高的性能指标源于探头设计,它由一个空心硅尖端和一个在尖端处垂直方向的热电偶传感器组成(低热质量),通过金属纳米线(50nm 直径)与样品相互作用,从而实现高横向分辨率。通过对嵌入二氧化硅核壳中的金属纳米结构、涂有聚合物薄膜的金属纳米结构以及金属-聚合物互连结构进行成像,证明了这种 SThM 方法的有效性。探头的纳米级间距和极小的热质量有望显著提高现有方法的性能,并在半导体工业、生物医学成像和数据存储等多个领域得到广泛应用。