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连续波室温金刚石激射器。

Continuous-wave room-temperature diamond maser.

机构信息

Department of Materials, Imperial College London, Exhibition Road, London SW7 2AZ, UK.

London Centre for Nanotechnology, Imperial College London, Exhibition Road, London SW7 2AZ, UK.

出版信息

Nature. 2018 Mar 21;555(7697):493-496. doi: 10.1038/nature25970.

DOI:10.1038/nature25970
PMID:29565362
Abstract

The maser-the microwave progenitor of the optical laser-has been confined to relative obscurity owing to its reliance on cryogenic refrigeration and high-vacuum systems. Despite this, it has found application in deep-space communications and radio astronomy owing to its unparalleled performance as a low-noise amplifier and oscillator. The recent demonstration of a room-temperature solid-state maser that utilizes polarized electron populations within the triplet states of photo-excited pentacene molecules in a p-terphenyl host paves the way for a new class of maser. However, p-terphenyl has poor thermal and mechanical properties, and the decay rates of the triplet sublevel of pentacene mean that only pulsed maser operation has been observed in this system. Alternative materials are therefore required to achieve continuous emission: inorganic materials that contain spin defects, such as diamond and silicon carbide, have been proposed. Here we report a continuous-wave room-temperature maser oscillator using optically pumped nitrogen-vacancy defect centres in diamond. This demonstration highlights the potential of room-temperature solid-state masers for use in a new generation of microwave devices that could find application in medicine, security, sensing and quantum technologies.

摘要

由于依赖于低温制冷和高真空系统,微波激射器——光学激光的微波前体——一直处于相对默默无闻的状态。尽管如此,由于其作为低噪声放大器和振荡器的无与伦比的性能,它还是在深空通信和射电天文学中找到了应用。最近,在 p-三联苯基质中利用光激发的五苯分子的三重态中的极化电子群体展示了一种室温固态微波激射器,为一类新的微波激射器铺平了道路。然而,p-三联苯的热学和力学性能较差,而且五苯分子的三重子亚层的衰减率意味着,在这个系统中只能观察到脉冲微波激射器的运转。因此,需要替代材料来实现连续发射:已经提出了包含自旋缺陷的无机材料,如金刚石和碳化硅。在这里,我们报告了一种使用金刚石中光学泵浦的氮空位缺陷中心的连续波室温微波激射振荡器。这一演示突出了室温固态微波激射器在新一代微波器件中的应用潜力,这些器件可能在医学、安全、传感和量子技术中找到应用。

相似文献

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Continuous-wave room-temperature diamond maser.连续波室温金刚石激射器。
Nature. 2018 Mar 21;555(7697):493-496. doi: 10.1038/nature25970.
2
Room-temperature solid-state maser.室温固态微波激射器。
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3
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本文引用的文献

1
Nanosecond time-resolved characterization of a pentacene-based room-temperature MASER.基于并五苯的室温 MASER 的纳秒时间分辨特性研究。
Sci Rep. 2017 Feb 7;7:41836. doi: 10.1038/srep41836.
2
High-frequency pulsed ENDOR spectroscopy of the NV(-) centre in the commercial HPHT diamond.商用高温高压合成钻石中NV(-) 中心的高频脉冲电子核双共振光谱
J Magn Reson. 2016 Jan;262:15-19. doi: 10.1016/j.jmr.2015.11.005. Epub 2015 Dec 2.
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Proposal for a room-temperature diamond maser.室温金刚石微波激射器的提案。
Sci Rep. 2024 Sep 28;14(1):22421. doi: 10.1038/s41598-024-73118-z.
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Tailoring Coherent Microwave Emission from a Solid-State Hybrid System for Room-Temperature Microwave Quantum Electronics.为室温微波量子电子学定制固态混合系统的相干微波发射。
Adv Sci (Weinh). 2024 Sep;11(35):e2401904. doi: 10.1002/advs.202401904. Epub 2024 Jul 15.
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Terahertz emission from diamond nitrogen-vacancy centers.金刚石氮空位中心的太赫兹辐射。
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Observation of magnetic amplification using dark spins.利用暗自旋观测磁放大
Proc Natl Acad Sci U S A. 2024 Apr 23;121(17):e2315696121. doi: 10.1073/pnas.2315696121. Epub 2024 Apr 19.
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Exploring the impact of stress on the electronic structure and optical properties of graphdiyne nanoribbons for advanced optoelectronic applications.探索应力对用于先进光电子应用的石墨炔纳米带的电子结构和光学性质的影响。
Sci Rep. 2024 Mar 13;14(1):6051. doi: 10.1038/s41598-024-56380-z.
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N-Heteroacenes as an Organic Gain Medium for Room-Temperature Masers.作为室温微波激射器有机增益介质的氮杂并苯
Chem Mater. 2023 May 23;35(11):4498-4509. doi: 10.1021/acs.chemmater.3c00640. eCollection 2023 Jun 13.
9
Microporous poly- and monocrystalline diamond films produced from chemical vapor deposited diamond-germanium composites.由化学气相沉积的金刚石-锗复合材料制成的微孔多晶和单晶金刚石薄膜。
Nanoscale Adv. 2023 Jan 24;5(5):1307-1315. doi: 10.1039/d2na00688j. eCollection 2023 Feb 28.
10
Diamond-based microwave quantum amplifier.基于金刚石的微波量子放大器。
Sci Adv. 2022 Dec 9;8(49):eade6527. doi: 10.1126/sciadv.ade6527. Epub 2022 Dec 7.
Nat Commun. 2015 Sep 23;6:8251. doi: 10.1038/ncomms9251.
4
Enhanced magnetic Purcell effect in room-temperature masers.室温微波激射器中增强的磁珀塞尔效应。
Nat Commun. 2015 Feb 20;6:6215. doi: 10.1038/ncomms7215.
5
Temperature- and magnetic-field-dependent longitudinal spin relaxation in nitrogen-vacancy ensembles in diamond.金刚石中氮空位团簇的温标和磁场依赖的纵向自旋弛豫。
Phys Rev Lett. 2012 May 11;108(19):197601. doi: 10.1103/PhysRevLett.108.197601.
6
Room-temperature solid-state maser.室温固态微波激射器。
Nature. 2012 Aug 16;488(7411):353-6. doi: 10.1038/nature11339.
7
Nanoscale magnetic sensing with an individual electronic spin in diamond.利用金刚石中的单个电子自旋进行纳米级磁传感。
Nature. 2008 Oct 2;455(7213):644-7. doi: 10.1038/nature07279.
8
Quenching spin decoherence in diamond through spin bath polarization.通过自旋池极化抑制金刚石中的自旋退相干
Phys Rev Lett. 2008 Jul 25;101(4):047601. doi: 10.1103/PhysRevLett.101.047601. Epub 2008 Jul 23.
9
Two-photon excited fluorescence of nitrogen-vacancy centers in proton-irradiated type Ib diamond.质子辐照 Ib 型金刚石中氮空位中心的双光子激发荧光
J Phys Chem A. 2007 Sep 27;111(38):9379-86. doi: 10.1021/jp073938o. Epub 2007 Aug 18.
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Coherent dynamics of coupled electron and nuclear spin qubits in diamond.金刚石中耦合电子与核自旋量子比特的相干动力学
Science. 2006 Oct 13;314(5797):281-5. doi: 10.1126/science.1131871. Epub 2006 Sep 14.