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本文引用的文献

1
Fourier transform ion cyclotron resonance mass spectrometrical analysis of raw fermented cocoa beans of Cameroon and Ivory Coast origin.对原产于喀麦隆和象牙海岸的未加工发酵可可豆进行傅里叶变换离子回旋共振质谱分析。
Food Res Int. 2014 Oct;64:958-961. doi: 10.1016/j.foodres.2014.07.012. Epub 2014 Aug 1.
2
High performance liquid chromatography (HPLC) fingerprints and primary structure identification of corn peptides by HPLC-diode array detection and HPLC-electrospray ionization tandem mass spectrometry.玉米肽的高效液相色谱(HPLC)指纹图谱及通过HPLC-二极管阵列检测和HPLC-电喷雾电离串联质谱进行一级结构鉴定
J Food Drug Anal. 2016 Jan;24(1):95-104. doi: 10.1016/j.jfda.2015.05.005. Epub 2015 Jul 22.
3
Protective effect of procyanidins extracted from the lotus seedpod on immune function injury induced by extremely low frequency electromagnetic field.莲房原花青素对极低频电磁场诱导免疫功能损伤的保护作用。
Biomed Pharmacother. 2016 Aug;82:364-72. doi: 10.1016/j.biopha.2016.05.021. Epub 2016 May 26.
4
Characterization and preparation of oligomeric procyanidins from Litchi chinensis pericarp.荔枝果皮中低聚原花青素的表征与制备
Fitoterapia. 2016 Jul;112:168-74. doi: 10.1016/j.fitote.2016.06.001. Epub 2016 Jun 7.
5
Molecular ion index assisted comprehensive profiling of B-type oligomeric proanthocyanidins in rhubarb by high performance liquid chromatography-tandem mass spectrometry.分子离子指数辅助高效液相色谱-串联质谱法对大黄中B型低聚原花青素进行全面分析
Anal Bioanal Chem. 2016 May;408(13):3555-70. doi: 10.1007/s00216-016-9433-z. Epub 2016 Mar 1.
6
Isolation and quantification of oligomeric and polymeric procyanidins in leaves and flowers of Hawthorn (Crataegus spp.).山楂(Crataegus spp.)叶片和花朵中低聚和聚合原花青素的分离与定量分析。
Fitoterapia. 2015 Jul;104:14-22. doi: 10.1016/j.fitote.2015.04.010. Epub 2015 Apr 25.
7
Screening of Anthocyanins and Anthocyanin-Derived Pigments in Red Wine Grape Pomace Using LC-DAD/MS and MALDI-TOF Techniques.采用液相色谱-二极管阵列检测/质谱联用(LC-DAD/MS)和基质辅助激光解吸电离飞行时间质谱(MALDI-TOF)技术对红葡萄酒葡萄皮渣中的花色苷和花色苷衍生色素进行筛选。
J Agric Food Chem. 2015 Sep 9;63(35):7636-44. doi: 10.1021/acs.jafc.5b00256. Epub 2015 May 13.
8
Interactions of polyphenols with carbohydrates, lipids and proteins.多酚与碳水化合物、脂质和蛋白质的相互作用。
Food Chem. 2015 May 15;175:556-67. doi: 10.1016/j.foodchem.2014.12.013. Epub 2014 Dec 11.
9
Rapid qualitative and quantitative analyses of proanthocyanidin oligomers and polymers by UPLC-MS/MS.采用超高效液相色谱-串联质谱法对原花青素低聚物和聚合物进行快速定性和定量分析。
J Agric Food Chem. 2014 Apr 16;62(15):3390-9. doi: 10.1021/jf500745y. Epub 2014 Apr 2.
10
Oxidative conversion of B- to A-type procyanidin trimer: evidence for quinone methide mechanism.B-型原花青素三聚体的氧化转化:醌甲醚机制的证据。
Food Chem. 2014 Jul 1;154:315-22. doi: 10.1016/j.foodchem.2014.01.018. Epub 2014 Jan 17.

原花青素:一篇通过质谱法进行结构解析的全面综述。

Procyanidins: a comprehensive review encompassing structure elucidation via mass spectrometry.

作者信息

Rue Emily A, Rush Michael D, van Breemen Richard B

机构信息

University of Illinois College of Pharmacy, 833 S Wood St, Chicago, Il, 60612, USA.

出版信息

Phytochem Rev. 2018 Feb;17(1):1-16. doi: 10.1007/s11101-017-9507-3. Epub 2017 May 9.

DOI:10.1007/s11101-017-9507-3
PMID:29651231
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5891158/
Abstract

Procyanidins are polyphenols abundant in dietary fruits, vegetables, nuts, legumes, and grains with a variety of chemopreventive biological effects. Rapid structure determination of these compounds is needed, notably for the more complex polymeric procyanidins. We review the recent developments in the structure elucidation of procyanidins with a focus on mass spectrometric approaches, especially liquid chromatography-tandem mass spectrometry (LC-MS/MS) and matrix-assisted laser desorption ionization (MALDI) MS/MS.

摘要

原花青素是一类在膳食水果、蔬菜、坚果、豆类和谷物中含量丰富的多酚类物质,具有多种化学预防生物学效应。需要对这些化合物进行快速结构测定,尤其是对于更为复杂的聚合原花青素。我们综述了原花青素结构解析方面的最新进展,重点关注质谱方法,特别是液相色谱-串联质谱法(LC-MS/MS)和基质辅助激光解吸电离(MALDI)MS/MS。