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功能化 MXene 材料:其应用进展。

Functional MXene Materials: Progress of Their Applications.

机构信息

The College of Chemistry and Chemical Engineering, Yangzhou University, 180 Si-Wang-Ting Road, Yangzhou, 225002, P. R. China.

School of Mathematical and Physical Sciences, University of Technology Sydney, City Campus, Broadway, Sydney, NSW, 2007, Australia.

出版信息

Chem Asian J. 2018 Oct 4;13(19):2742-2757. doi: 10.1002/asia.201800543. Epub 2018 Aug 23.

DOI:10.1002/asia.201800543
PMID:30047591
Abstract

Nowadays, two-dimensional materials have many applications in materials science. As a novel two-dimensional layered material, MXene possesses distinct structural, electronic, and chemical properties; thus, it has potential applications in many fields, including battery electrodes, energy storage materials, sensors, and catalysts. Up to now, more than 70 MAX phases have been reported. However, in contrast to the variety of MAX phases, the existing MXene family merely includes Ti C, Ti C , (Ti , Nb ) C, (V , Cr ) C , Nb C, Ti CN, Ta C , V C, and Nb C . Among these materials, the Ti C T MXene exhibits prominently high volumetric capacitance, and the rate at which it transports electron is suitable for electrode materials in batteries and supercapacitors. Hence, Ti C T is commonly utilized as an electrode material in ion batteries such as Li , Na , K , Mg , Ca , and Al batteries. What is more, Ti C has the biggest specific surface area among all of these potential MXene phases, and therefore, Ti C has remarkably high gravimetric hydrogen storage capacities. In addition, Ti CO materials display extremely high activity for CO oxidation, which makes it possible to design catalysts for CO oxidation at low temperatures. Furthermore, Ti C T with O, OH, and/or F terminations can be used for water purification owing to excellent water permeance, favorable filtration ability, and long-time operation ability. This review supplies a relatively comprehensive summary of various applications of MXenes over the past few years.

摘要

如今,二维材料在材料科学中有许多应用。作为一种新型的二维层状材料,MXene 具有独特的结构、电子和化学性质;因此,它在许多领域有潜在的应用,包括电池电极、储能材料、传感器和催化剂。迄今为止,已经报道了超过 70 种 MAX 相。然而,与 MAX 相的多样性相比,现有的 MXene 家族仅包括 TiC、Ti 3 C 2 T X、(Ti, Nb)C、(V, Cr)C、NbC、TiCN、TaC、VC 和 NbC。在这些材料中,Ti 3 C 2 T MXene 表现出突出的高体积电容,其电子传输速率适合电池和超级电容器中的电极材料。因此,Ti 3 C 2 T 通常用作锂离子电池、钠离子电池、钾离子电池、镁离子电池、钙离子电池和铝离子电池等的电极材料。此外,TiC 是所有潜在 MXene 相中比表面积最大的,因此具有极高的重量储氢容量。此外,TiCO 材料对 CO 氧化具有极高的活性,这使得设计低温 CO 氧化催化剂成为可能。此外,具有 O、OH 和/或 F 端基的 Ti 3 C 2 T 可以用于水净化,因为它具有极好的水透过率、良好的过滤能力和长时间运行能力。本文综述了 MXenes 在过去几年中的各种应用。

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