Wang Xu, Li Jiawei, Huang Yubing, Zhu Jiayi, Hu Rongrong, Wu Wanqing, Jiang Huanfeng
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering , South China University of Technology , Guangzhou 510640 , China.
State Key Laboratory of Luminescent Materials and Devices , South China University of Technology , Guangzhou 510640 , China.
J Org Chem. 2018 Sep 7;83(17):10453-10464. doi: 10.1021/acs.joc.8b01494. Epub 2018 Aug 24.
A new transition-metal-free version for the synthesis of π-conjugated quinazoline-substituted ethene derivatives from readily available starting materials has been developed. Quinazoline-substituted ethenes were obtained in moderate to high yields with completely Z-selectivity, and the resulting quinazoline-substituted ethenes show typical aggregation-induced emission (AIE) properties.
已开发出一种新型无过渡金属的方法，可从容易获得的起始原料合成π-共轭喹唑啉取代的乙烯衍生物。以中等至高产率获得了具有完全Z选择性的喹唑啉取代的乙烯，并且所得的喹唑啉取代的乙烯表现出典型的聚集诱导发光（AIE）特性。
