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通过在具有低可见光反射率的硅纳米线阵列上均匀装饰氧化铜纳米颗粒制备的高效光催化剂。

Efficient Photocatalysts Made by Uniform Decoration of CuO Nanoparticles on Si Nanowire Arrays with Low Visible Reflectivity.

作者信息

Tang Chien-Hsin, Hsiao Po-Hsuan, Chen Chia-Yun

机构信息

Department of Materials Science and Engineering, National Cheng Kung University, Tainan, 70101, Taiwan.

Hierarchical Green-Energy Materials (Hi-GEM) Research Center, National Cheng Kung University, Tainan, 70101, Taiwan.

出版信息

Nanoscale Res Lett. 2018 Oct 4;13(1):312. doi: 10.1186/s11671-018-2735-7.

DOI:10.1186/s11671-018-2735-7
PMID:30288628
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6172162/
Abstract

Highly uniformed decorations of CuO nanoparticles on the sidewalls of silicon nanowires (SiNWs) with high aspect ratio were prepared through a two-step electroless deposition at room temperature. Morphology evolutions and photocatalytic performance of SiNWs decorated with aggregated and dispersed CuO nanoparticles were unveiled, and the correlated photodegradation kinetics was identified. In comparison with the conventional direct loadings where the aggregated CuO/SiNW structures were created, the uniform incorporation of CuO with SiNWs exhibited more than three and nine times of improved photodegradation efficiency than the aggregated-CuO/SiNWs and sole SiNWs, respectively.

摘要

通过室温下的两步化学沉积法,在具有高纵横比的硅纳米线(SiNWs)侧壁上制备了高度均匀的氧化铜纳米颗粒装饰层。揭示了聚集和分散的氧化铜纳米颗粒装饰的硅纳米线的形貌演变和光催化性能,并确定了相关的光降解动力学。与形成聚集的CuO/SiNW结构的传统直接负载方法相比,氧化铜与硅纳米线的均匀结合分别比聚集的CuO/SiNWs和单一的硅纳米线表现出提高了三倍和九倍以上的光降解效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/4b02c6d0b377/11671_2018_2735_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/cd688a5bde4b/11671_2018_2735_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/39bdde79254a/11671_2018_2735_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/9127a7d6e7e0/11671_2018_2735_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/4b02c6d0b377/11671_2018_2735_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/cd688a5bde4b/11671_2018_2735_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/39bdde79254a/11671_2018_2735_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/9127a7d6e7e0/11671_2018_2735_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/750c/6172162/4b02c6d0b377/11671_2018_2735_Fig4_HTML.jpg

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