Kao Yu-Cheng, Chou Hao-Ming, Hsu Shun-Chieh, Lin Albert, Lin Chien-Chung, Shih Zun-Hao, Chang Chun-Ling, Hong Hwen-Fen, Horng Ray-Hua
Graduate Institute of Precision Engineering, National Chung Hsing University, Taichung, 40227, Taiwan, Republic of China.
Institute of Electronics, National Chiao Tung University, Hsinchu, 30010, Taiwan, Republic of China.
Sci Rep. 2019 Mar 13;9(1):4308. doi: 10.1038/s41598-019-40727-y.
The integration of III-V and Si multi-junction solar cells as photovoltaic devices has been studied in order to achieve high photovoltaic conversion efficiency. However, large differences in the coefficients of thermal expansion and the lattice parameters of GaAs, Si, and InGaAs have made it difficult to obtain high-efficiency solar cells grown as epilayers on Si and InP substrates. In this paper, two types of devices, including GaInP/GaAs stacked on Si (GaInP/GaAs//Si) and GaInP/GaAs stacked on InGaAs (GaInP/GaAs//InGaAs), are fabricated via mechanical stacking and wire bonding technologies. Mechanically stacked GaInP/GaAs//Si and GaInP/GaAs//InGaAs triple-junction solar cells are prepared via glue bonding. Current-voltage measurements of the two samples are made at room temperature. The short-circuit current densities of the GaInP/GaAs//Si and GaInP/GaAs//InGaAs solar cells are 13.37 and 13.66 mA/cm, while the open-circuit voltages of these two samples are measured to be 2.71 and 2.52 V, respectively. After bonding the GaInP/GaAs dual-junction with the Si and InGaAs solar cells, the conversion efficiency is relatively improved by 32.6% and 30.9%, respectively, compared to the efficiency of the GaInP/GaAs dual-junction solar cell alone. This study demonstrates the high potential of combining mechanical stacked with wire bonding and ITO films to achieve high conversion efficiency in solar cells with three or more junctions.
为了实现高的光伏转换效率,人们对III-V族与硅多结太阳能电池作为光电器件的集成进行了研究。然而,砷化镓、硅和铟镓砷的热膨胀系数和晶格参数存在很大差异,这使得在硅和磷化铟衬底上生长高效外延层太阳能电池变得困难。在本文中,通过机械堆叠和引线键合技术制造了两种类型的器件,包括堆叠在硅上的镓铟磷/砷化镓(镓铟磷/砷化镓//硅)和堆叠在铟镓砷上的镓铟磷/砷化镓(镓铟磷/砷化镓//铟镓砷)。通过胶接制备了机械堆叠的镓铟磷/砷化镓//硅和镓铟磷/砷化镓//铟镓砷三结太阳能电池。在室温下对这两个样品进行了电流-电压测量。镓铟磷/砷化镓//硅和镓铟磷/砷化镓//铟镓砷太阳能电池的短路电流密度分别为13.37和13.66 mA/cm,而这两个样品的开路电压分别测量为2.71和2.52 V。将镓铟磷/砷化镓双结与硅和铟镓砷太阳能电池键合后,与单独的镓铟磷/砷化镓双结太阳能电池的效率相比,转换效率分别相对提高了32.6%和30.9%。这项研究证明了将机械堆叠与引线键合和ITO薄膜相结合在具有三个或更多结的太阳能电池中实现高转换效率的巨大潜力。