Department of Health Science, Korea University, Anam-ro 145, Seongbuk-gu, Seoul 02841, Korea.
Accident Prevention and Assessment Division,90 Gajeongbuk-ro, Yuseong-gu, Daejeon 34111, Korea.
Int J Environ Res Public Health. 2019 Sep 5;16(18):3260. doi: 10.3390/ijerph16183260.
Industrial chemicals differ in their treatment methods and types, depending on their physicochemical properties. Highly volatile chemicals are emitted despite installation of preventive facilities, such as scrubbers and adsorption towers. Some countries release a Toxic Release Inventory (TRI), which is a mandatory report on the amount of chemicals emitted annually. This report is released to the citizens to ensure their right to knowledge and life. Numerous methods have been devised to investigate the amount of chemical emissions. There are four methods to estimate TRI emissions (Emission Factor Method; Material Balance Method; Source Testing Method; Emission Model Method). Moreover, efforts have been made to increase awareness and formulate plans to reduce chemical emissions. Despite this, the TRI method tends to underestimate and overestimate, especially due to volatile compounds. If the results of the TRI emissions are underestimated, toxic chemicals can have a negative impact on citizens. Volatile compounds are commonly used in chemical manufacturing plants, such as paint plants. In this study, a suitable method for each industrial process was suggested based on conservative estimates of multiple toxic chemical inventory method, focusing on the paint manufacturing process. In the paint manufacturing plant, storage, weighing, and mixing processes should be used emission model method to estimate TRI. In the reaction process, TRI must be estimated by the source test method. In the transfer process, the emission factor method should be used to estimate TRI. In the atmosphere prevention process, the emission factor method or source testing method should be used depending on the physical and chemical properties such as vapor pressure of the chemical.
工业化学品因其物理化学性质的不同,其处理方法和类型也有所不同。尽管安装了洗涤器和吸附塔等预防设施,高挥发性化学品仍会逸出。一些国家会发布有毒物质释放清单(TRI),这是一份关于每年排放的化学物质数量的强制性报告。该报告向公民发布,以确保他们的知情权和生命权。已经设计了许多方法来调查化学排放量。有四种方法可以估算 TRI 排放量(排放因子法;物质平衡法;源测试法;排放模型法)。此外,还努力提高认识并制定计划以减少化学排放量。尽管如此,TRI 方法往往会低估和高估排放量,尤其是对于挥发性化合物。如果 TRI 排放量的结果被低估,有毒化学物质可能会对公民产生负面影响。挥发性化合物在化学制造工厂中很常见,例如涂料厂。在这项研究中,根据多种有毒化学物质清单方法的保守估计,针对涂料制造过程,为每个工业过程提出了一种合适的方法。在涂料制造工厂中,应使用排放模型法来估算存储、称重和混合过程中的 TRI。在反应过程中,必须通过源测试方法来估算 TRI。在转移过程中,应使用排放因子法来估算 TRI。在大气防治过程中,应根据化学物质的蒸气压等物理化学性质,使用排放因子法或源测试法来估算 TRI。