Flejszar Monika, Chmielarz Paweł
Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland.
Materials (Basel). 2019 Sep 18;12(18):3030. doi: 10.3390/ma12183030.
Surface-initiated atom transfer radical polymerization (SI-ATRP) is a powerful tool that allows for the synthesis of organic-inorganic hybrid nanomaterials with high potential applications in many disciplines. This review presents synthetic achievements and modifications of nanoparticles SI-ATRP described in literature last decade. The work mainly focuses on the research development of silica, gold and iron polymer-grafted nanoparticles as well as nature-based materials like nanocellulose. Moreover, typical single examples of nanoparticles modification, i.e., ZnO, are presented. The organic-inorganic hybrid systems received according to the reversible deactivation radical polymerization (RDRP) approach with drastically reduced catalyst complex concentration indicate a wide range of applications of materials including biomedicine and microelectronic devices.
表面引发原子转移自由基聚合（SI-ATRP）是一种强大的工具，可用于合成在许多学科中具有高潜在应用价值的有机-无机杂化纳米材料。本综述介绍了过去十年文献中描述的纳米粒子SI-ATRP的合成成果和改性方法。这项工作主要集中在二氧化硅、金和铁聚合物接枝纳米粒子以及纳米纤维素等天然材料的研究进展上。此外，还介绍了纳米粒子改性的典型单一实例，即氧化锌。通过可逆失活自由基聚合（RDRP）方法获得的有机-无机杂化体系，其催化剂络合物浓度大幅降低，表明该材料在生物医学和微电子器件等领域具有广泛的应用。
