Influence of Carrier Gases on the Quality of Epitaxial Corundum-Structured α-GaO Films Grown by Mist Chemical Vapor Deposition Method.

This report systematically investigates the influence of different carrier gases (O, N, and air) on the growth of gallium oxide (GaO) thin films on c-plane sapphire substrates by using the mist-CVD method. Although XRD and Raman measurements show that the pure corundum-structured α-GaO with single (0006) plane orientation was successfully obtained for all three different carrier gases, the crystal quality could be greatly affected by the carrier gas. When O is used as the carrier gas, the smallest full-width at half maximum (FWHM), the very sharp absorption cutoff edge, the perfect lattice structure, the highest growth rate, and the smooth surface can be obtained for the epitaxial α-GaO film as demonstrated by XRD, UV-VIS, TEM, AFM (Atomic Force Microscope), and SEM measurements. It is proposed that the oxygen content in carrier gas should be responsible for all of these results. XPS (X-ray photoelectron spectroscopy) analysis also confirms that more oxygen elements can be included in epitaxial film when O is used as the carrier gas and thus help improve the crystal quality. The proper carrier gas is essential for the high quality α-GaO growth.