Hoover Gabrielle C, Seferos Dwight S
Department of Chemistry , University of Toronto , 80 St. George Street , ON M5S 3H6 , Canada . Email:
Department of Chemical Engineering and Applied Chemistry , University of Toronto , 200 College Street , Ontario M5S 3E5 , Canada.
Chem Sci. 2019 Oct 7;10(40):9182-9188. doi: 10.1039/c9sc04279b. eCollection 2019 Oct 28.
Sulfur-containing compounds, particularly derivatives of thiophene, are well studied for organic optoelectronic applications. Incorporating selenium or tellurium in place of sulfur imparts different physical properties due to the fundamental differences of these atoms relative to their lighter analogues. This has a profound influence on the properties of molecules and materials that incorporate chalcogens that may ultimately lead to new opportunities and applications. This mini-review will focus on the quantitative and qualitative photophysical characteristics of organic materials containing selenium and tellurium as well as their emerging applications as molecular photoactive species, including light-emitting sensors, triplet sensitizers, and beyond.
含硫化合物,特别是噻吩衍生物,在有机光电子应用方面已得到充分研究。用硒或碲取代硫会赋予不同的物理性质,这是由于这些原子与其较轻的类似物存在根本差异。这对包含硫族元素的分子和材料的性质有深远影响,最终可能带来新的机遇和应用。本综述将聚焦于含硒和碲有机材料的定量和定性光物理特性,以及它们作为分子光活性物种的新兴应用,包括发光传感器、三重态敏化剂等。