State Key Laboratory of Physical Chemistry of Solid Surfaces, The MOE Laboratory of Spectrochemical Analysis & Instrumentation, The Key Laboratory for Chemical Biology of Fujian Province, and Department of Chemical Biology, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Chem Commun (Camb). 2020 Apr 9;56(29):4106-4109. doi: 10.1039/d0cc00778a.
Herein we report a pair of redox-responsive manganese complexes Mn(iii)/(ii)-N,N'-bis(2-hydroxy-4-trifluoromethylbenzyl)ethylenediamine-N,N'-diacetate (HTFBED, L1), which are water soluble and biologically interconvertible, as reversible redox-responsive probes in 1H/19F MRI for detecting and imaging biological redox species, offering a means to access valuable redox information associated with various diseases.
在此，我们报告了一对氧化还原响应性锰配合物 Mn(iii)/(ii)-N,N'-双(2-羟基-4-三氟甲基苄基)乙二胺-N,N'-二乙酸盐（HTFBED，L1），它们水溶性好且可生物转化，可用作 1H/19F MRI 中检测和成像生物氧化还原物种的可逆氧化还原响应探针，为获取与各种疾病相关的有价值的氧化还原信息提供了一种手段。
