金属硫氧化物：从块状化合物到纳米材料

Larquet Clément, Carenco Sophie

Sorbonne Université, CNRS, Collège de France, Laboratoire de Chimie de la Matière Condensée de Paris, LCMCP, Paris, France.

Sorbonne Université, CNRS, IRD, MNHN, Institut de Minéralogie, de Physique des Matériaux et de Cosmologie, IMPMC, Paris, France.

Front Chem. 2020 Mar 31;8:179. doi: 10.3389/fchem.2020.00179. eCollection 2020.

This review summarizes the syntheses and applications of metal oxysulfides. Bulk compounds of rare earth and transition metals are discussed in the section Introduction. After a presentation of their main properties and applications, their structures are presented and their syntheses are discussed. The section Bulk Materials and Their Main Applications is dedicated to the growing field of nanoscaled metal oxysulfides. Synthesis and applications of lanthanide-based nanoparticles are more mature and are discussed first. Then, works on transition-metal based nanoparticles are presented and discussed. Altogether, this review highlights the opportunities offered by metal oxysulfides for application in a range of technological fields, in relation with the most advanced synthetic routes and characterization techniques.

本综述总结了金属氧硫化物的合成与应用。在引言部分讨论了稀土和过渡金属的块状化合物。在介绍了它们的主要性质和应用之后，阐述了它们的结构并讨论了其合成方法。“块状材料及其主要应用”部分专门介绍了纳米级金属氧硫化物这一不断发展的领域。基于镧系元素的纳米粒子的合成与应用更为成熟，首先进行讨论。然后，介绍并讨论了基于过渡金属的纳米粒子的研究工作。总之，本综述强调了金属氧硫化物在一系列技术领域应用中所提供的机遇，以及与之相关的最先进的合成路线和表征技术。