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采用电化学方法测定水果提取物中的熊果酸。

Determination of Ursolic Acid in Extracts From Fruit Using an Electrochemical Method.

作者信息

Feng Yingpu, Wei Zheng, Zhang Junping

机构信息

Centre of Cerebrovascular, Zhengzhou University People's Hospital, Zhengzhou, China.

Centre of Cerebrovascular, Henan Provincial People's Hospital, Zhengzhou, China.

出版信息

Front Chem. 2020 May 27;8:444. doi: 10.3389/fchem.2020.00444. eCollection 2020.

Abstract

In this work, we reported a facile wet chemical method for depositing Pt nanoparticles on the surface of boron nitride nanosheets (BNNS-Pt NPs). The deposited nanocomposite was applied for glassy carbon electrode surface modification. The modified electrode was then used for detecting ursolic acid (UA). The results indicate that the BNNS-Pt NPs exhibited excellent electrocatalytic activity toward UA oxidation compared with that of the bare glassy carbon electrode (GCE) and Pt NPs/GCE. The UA oxidation currents is linearly related its concentration from 1 to 1,200 pM. The limit of detection can be calculated to be 0.5 pM. In addition, the UA sensor was also successfully used for the determination of UA in fruit samples.

摘要

在本工作中,我们报道了一种简便的湿化学方法,用于在氮化硼纳米片表面沉积铂纳米颗粒(BNNS-Pt NPs)。所沉积的纳米复合材料被应用于玻碳电极表面修饰。然后将修饰电极用于检测熊果酸(UA)。结果表明,与裸玻碳电极(GCE)和Pt NPs/GCE相比,BNNS-Pt NPs对UA氧化表现出优异的电催化活性。UA氧化电流与其浓度在1至1200 pM范围内呈线性关系。计算得出检测限为0.5 pM。此外,该UA传感器还成功用于水果样品中UA的测定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2555/7267720/f74de730ed44/fchem-08-00444-g0001.jpg

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