Sławiński J
Institute of Physics, Pedagogical University, Krakow, Poland.
Experientia. 1988 Jul 15;44(7):559-71. doi: 10.1007/BF01953303.
The fundamental laws of photochemistry and the essential results of experimental research on ultraweak cell radiation are presented. By comparing all the facts it can be concluded that the phenomena discussed may arise from a variety of possible reactions and sources. Recombination reactions of certain radicals actually do release sufficient energy to generate UV-photons of the intensity under consideration. On the other hand, stimulated emission cannot be excluded in view of the distinct deviation of the radiation field from thermal equilibrium. There exist, however, various other candidates, such as direct emitters like flavins, indoles, porphyrins, carbonyl derivatives and aromatic compounds, and molecular oxygen and its various species, as well as collective molecular interactions, e.g. dimole or exciplex transitions, triplet-triplet annihilation, collective hydrolysis, electric field effects in membranes, etc. Careful biochemical and biophysical experiments are still necessary to find answers to all the questions that remain; not only individual problems have to be solved, but it is important to keep in mind the interrelationships between certain reactions.
介绍了光化学的基本定律以及关于细胞超微弱辐射的实验研究的基本结果。通过比较所有事实可以得出结论,所讨论的现象可能源于多种可能的反应和来源。某些自由基的重组反应实际上确实释放出足够的能量来产生所考虑强度的紫外光子。另一方面,鉴于辐射场明显偏离热平衡,不能排除受激发射。然而,还存在各种其他候选因素,例如黄素、吲哚、卟啉、羰基衍生物和芳香化合物等直接发射体,以及分子氧及其各种形态,还有集体分子相互作用,如双分子或激基复合物跃迁、三重态-三重态湮灭、集体水解、膜中的电场效应等。仍然需要进行仔细的生化和生物物理实验,以找到所有遗留问题的答案;不仅要解决个别问题,而且重要的是要牢记某些反应之间的相互关系。