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用于柔性机电设备的聚偏氟乙烯复合材料、制备及应用综述

Composites, Fabrication and Application of Polyvinylidene Fluoride for Flexible Electromechanical Devices: A Review.

作者信息

Guo Shuaibing, Duan Xuexin, Xie Mengying, Aw Kean Chin, Xue Qiannan

机构信息

State Key Laboratory of Precision Measuring Technology & Instruments, College of Precision Instrument and Opto-Electronics Engineering, Tianjin University, Tianjin 300072, China.

Department Mechanical Engineering, University of Auckland, Auckland 1023, New Zealand.

出版信息

Micromachines (Basel). 2020 Dec 3;11(12):1076. doi: 10.3390/mi11121076.

DOI:10.3390/mi11121076
PMID:33287450
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7761858/
Abstract

The technological development of piezoelectric materials is crucial for developing wearable and flexible electromechanical devices. There are many inorganic materials with piezoelectric effects, such as piezoelectric ceramics, aluminum nitride and zinc oxide. They all have very high piezoelectric coefficients and large piezoelectric response ranges. The characteristics of high hardness and low tenacity make inorganic piezoelectric materials unsuitable for flexible devices that require frequent bending. Polyvinylidene fluoride (PVDF) and its derivatives are the most popular materials used in flexible electromechanical devices in recent years and have high flexibility, high sensitivity, high ductility and a certain piezoelectric coefficient. Owing to increasing the piezoelectric coefficient of PVDF, researchers are committed to optimizing PVDF materials and enhancing their polarity by a series of means to further improve their mechanical-electrical conversion efficiency. This paper reviews the latest PVDF-related optimization-based materials, related processing and polarization methods and the applications of these materials in, e.g., wearable functional devices, chemical sensors, biosensors and flexible actuator devices for flexible micro-electromechanical devices. We also discuss the challenges of wearable devices based on flexible piezoelectric polymer, considering where further practical applications could be.

摘要

压电材料的技术发展对于可穿戴和柔性机电设备的开发至关重要。有许多具有压电效应的无机材料，如压电陶瓷、氮化铝和氧化锌。它们都具有非常高的压电系数和较大的压电响应范围。高硬度和低韧性的特性使得无机压电材料不适用于需要频繁弯曲的柔性设备。聚偏二氟乙烯（PVDF）及其衍生物是近年来柔性机电设备中最常用的材料，具有高柔韧性、高灵敏度、高延展性和一定的压电系数。由于提高了PVDF的压电系数，研究人员致力于优化PVDF材料，并通过一系列手段增强其极性，以进一步提高其机电转换效率。本文综述了基于PVDF相关优化的最新材料、相关加工和极化方法，以及这些材料在可穿戴功能设备、化学传感器、生物传感器和用于柔性微机电设备的柔性致动器设备等方面的应用。我们还讨论了基于柔性压电聚合物的可穿戴设备面临的挑战，并考虑了其进一步的实际应用方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/d576b6c9106d/micromachines-11-01076-g014.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/b822f02d14c4/micromachines-11-01076-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/1976c8ff777f/micromachines-11-01076-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/d10141fa602a/micromachines-11-01076-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/51d6fd354bdc/micromachines-11-01076-g010.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/d576b6c9106d/micromachines-11-01076-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/4e5296090be3/micromachines-11-01076-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/427ba7af487c/micromachines-11-01076-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/0b536ffcc6f0/micromachines-11-01076-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/5ec86923c227/micromachines-11-01076-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/5081e2ac2f95/micromachines-11-01076-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/e971aa626b84/micromachines-11-01076-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/b822f02d14c4/micromachines-11-01076-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/1976c8ff777f/micromachines-11-01076-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/d10141fa602a/micromachines-11-01076-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/51d6fd354bdc/micromachines-11-01076-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/26419e60edcb/micromachines-11-01076-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/91829c52ca03/micromachines-11-01076-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/d8a2270c8894/micromachines-11-01076-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fa82/7761858/d576b6c9106d/micromachines-11-01076-g014.jpg

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