Li Chun, Zhang Lili, Chen Jiaqi, Li Xuelian, Sun Jingwen, Zhu Junwu, Wang Xin, Fu Yongsheng
Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing, 210094, China.
Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huai'an, Jiangsu 223300, China.
Nanoscale. 2021 Jan 21;13(2):485-509. doi: 10.1039/d0nr06396g.
Metal-organic frameworks (MOFs) have emerged as attractive materials for energy and environmental-related applications owing to their structural, chemical and functional diversity over the last two decades. It is known that the poor carrier mobility and low electrical conductivity of ordinary MOFs severely limit their utility in practical applications. In the past 10 years, several MOF materials with high carrier mobility and outstanding electrical conductivity have received a worldwide upsurge of research interest and many techniques and strategies have been used to synthesize such MOFs. In this critical review, we provide an overview of the significant advances in the development of conductive MOFs reported until now. Their theoretical and synthetic design strategies, conductive mechanisms, electrical transport measurements, and applications are systematically summarized and discussed. In addition, we will also give some discussions on challenges and perspectives in this exciting field.
在过去二十年中，金属有机框架（MOFs）因其结构、化学和功能的多样性，已成为能源和环境相关应用中具有吸引力的材料。众所周知，普通MOFs较差的载流子迁移率和低电导率严重限制了它们在实际应用中的效用。在过去十年里，几种具有高载流子迁移率和出色电导率的MOF材料受到了全球范围内的研究热潮，人们采用了许多技术和策略来合成此类MOFs。在这篇综述中，我们概述了迄今为止报道的导电MOFs发展中的重大进展。系统地总结和讨论了它们的理论和合成设计策略、导电机理、电输运测量及应用。此外，我们还将对这一令人兴奋的领域中的挑战和前景进行一些讨论。
