Department of Chemistry School of Science, Tianjin University, Tianjin 300354, China.
Institute for Materials Discovery, University College London, 107 Roberts Building, London WC1E 7JE, United Kingdom; Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, United Kingdom.
Int J Biol Macromol. 2021 Mar 15;173:225-243. doi: 10.1016/j.ijbiomac.2021.01.109. Epub 2021 Jan 20.
Nanogenerator is a promising energy harvesting device that can scavenge tiny mechanical energy from the surrounding environment, and then convert it into electricity. Natural bio-polymers are the potential candidates for the design of nanogenerators due to their excellent characteristics like piezoelectricity, triboelectricity, non-toxicity, biocompatibility and biodegradability. Especially, nanogenerators using bio-sourced polymers as the core raw materials are suitable for wearable and implantable devices. In this review, major advancements in the sensing field of nanogenerators based on natural polysaccharides and proteins (cellulose, chitosan, alginate, agarose, starch, lignin, silk fibroin, collagen, gelatin, keratin, peptide, M13 bacteriophage, β-cyclodextrin, spider silk, etc.) are summarized. Also, challenges in the improvement of electric output performance, flexibility, anti-humidity and energy management for natural polymers based-nanogenerators are proposed. In the future, they will be applied in daily life as an alternative for traditional power source after addressing issues mentioned above.
纳米发电机是一种很有前途的能量收集装置,它可以从周围环境中收集微小的机械能,然后将其转化为电能。由于具有压电性、摩擦电性、无毒、生物相容性和可生物降解性等优异特性,天然生物聚合物是纳米发电机设计的潜在候选材料。特别是,以生物来源聚合物为核心原料的纳米发电机适用于可穿戴和植入式设备。在这篇综述中,总结了基于天然多糖和蛋白质(纤维素、壳聚糖、海藻酸盐、琼脂糖、淀粉、木质素、丝纤维蛋白、胶原蛋白、明胶、角蛋白、肽、M13 噬菌体、β-环糊精、蜘蛛丝等)的纳米发电机在传感领域的主要进展。同时,还提出了提高基于天然聚合物的纳米发电机的电输出性能、灵活性、抗湿性和能量管理的挑战。在解决上述问题后,它们将作为传统电源的替代品应用于日常生活中。