Anchoring Metallic MoS Quantum Dots over MWCNTs for Highly Sensitive Detection of Postharvest Fungicide in Traditional Chinese Medicines.

Carbendazim, a very common contamination to the traditional Chinese medicines (TCMs), has posed serious threat to the environment and human health. However, sensitive and selective detection of carbendazim (MBC) in the TCMs is a big challenge for their complex chemical constituents. In this work, a 0D/1D nanohybrid was developed by anchoring 1T-phased MoS quantum dots (QDs) over multiwall carbon nanotubes (MWCNTs) via a facile assembly method. High-resolution transmission electron microscopy (HRTEM), Raman spectroscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis (TGA) together with EIS reveal that the 1T-phased QDs can anchor over MWCNTs via van der Waals forces, and the anchoring improves the nanohybrid surface area and conductivity. Therefore, the electrochemical sensor fabricated based on the MoS QDs@MWCNT nanohybrid shows excellent catalytic activity to MBC oxidation. Under optimized conditions, the sensor presents a linear voltammetry response to MBC concentration from 0.04 to 1.00 μmol·L, a low detection limit of 2.6 × 10 mol·L, as well as high selectivity, good reproducibility, and long-term stability. Moreover, the sensor has been successfully employed to determine MBC in two typical TCMs and the obtained recoveries are in good accordance with the results achieved by HPLC, showing that the constructed sensor plate holds great practical application in MBC analysis with complex matrix.