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共轭聚合物应用的新方法:多功能单线态氧分子的光激活源

New Approach in the Application of Conjugated Polymers: The Light-Activated Source of Versatile Singlet Oxygen Molecule.

作者信息

Blacha-Grzechnik Agata

机构信息

Faculty of Chemistry, Silesian University of Technology, Strzody 9, 44-100 Gliwice, Poland.

出版信息

Materials (Basel). 2021 Feb 26;14(5):1098. doi: 10.3390/ma14051098.

Abstract

For many years, the research on conjugated polymers (CPs) has been mainly focused on their application in organic electronics. Recent works, however, show that due to the unique optical and photophysical properties of CPs, such as high absorption in UV-Vis or even near-infrared (NIR) region and efficient intra-/intermolecular energy transfer, which can be relatively easily optimized, CPs can be considered as an effective light-activated source of versatile and highly reactive singlet oxygen for medical or catalytic use. The aim of this short review is to present the novel possibilities that lie dormant in those exceptional polymers with the extended system of π-conjugated bonds.

摘要

多年来,共轭聚合物(CPs)的研究主要集中在其在有机电子学中的应用。然而,最近的研究表明,由于CPs具有独特的光学和光物理性质,如在紫外-可见甚至近红外(NIR)区域的高吸收以及高效的分子内/分子间能量转移,且这些性质相对容易优化,CPs可被视为一种有效的光激活源,用于产生适用于医学或催化用途的多功能且高活性的单线态氧。这篇简短综述的目的是展示那些具有扩展π共轭键体系的特殊聚合物中潜藏的新可能性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e3e6/7956640/e6e60dbad11b/materials-14-01098-g001.jpg

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