Hejna Aleksander, Korol Jerzy, Kosmela Paulina, Kuzmin Anton, Piasecki Adam, Kulawik Arkadiusz, Chmielnicki Błażej
Department of Polymer Technology, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland.
Department of Material Engineering, Central Mining Institute, Pl. Gwarków 1, 40-166 Katowice, Poland.
Polymers (Basel). 2021 Mar 14;13(6):893. doi: 10.3390/polym13060893.
The present paper describes the application of two types of food-industry by-products, brewers' spent grain (BSG), and coffee silverskin (ŁK) as promising alternatives for the conventional beech wood flour (WF) for wood-polymer composites. The main goal was to investigate the impact of partial and complete WF substitution by BSG and ŁK on the processing, structure, physicochemical, mechanical, and thermal properties of resulting composites. Such modifications enabled significant enhancement of the melt flowability, which could noticeably increase the processing throughput. Replacement of WF with BSG and ŁK improved the ductility of composites, which affected their strength however. Such an effect was attributed to the differences in chemical composition of fillers, particularly the presence of proteins and lipids, which acted as plasticizers. Composites containing food-industry by-products were also characterized by the lower thermal stability compared to conventional WF. Nevertheless, the onset of decomposition exceeding 215 °C guarantees a safe processing window for polyethylene-based materials.
本文描述了两种食品工业副产品,即啤酒糟(BSG)和咖啡银皮(ŁK)作为传统山毛榉木粉(WF)用于木材聚合物复合材料的有前途的替代品的应用。主要目标是研究用BSG和ŁK部分和完全替代WF对所得复合材料的加工、结构、物理化学、机械和热性能的影响。这种改性显著提高了熔体流动性,这可以显著提高加工产量。用BSG和ŁK替代WF提高了复合材料的延展性,然而这也影响了它们的强度。这种效果归因于填料化学成分的差异,特别是蛋白质和脂质的存在,它们起到了增塑剂的作用。与传统WF相比,含有食品工业副产品的复合材料的热稳定性也较低。然而,超过215°C的分解起始温度保证了聚乙烯基材料的安全加工窗口。