Mehrara Rojin, Malekie Shahryar, Kotahi Seyed Mohsen Saleh, Kashian Sedigheh
Physics Department, K. N. Toosi University of Technology, Tehran, Iran.
Radiation Application Research School, Nuclear Science and Technology Research Institute (NSTRI), Tehran, Iran.
Sci Rep. 2021 May 19;11(1):10614. doi: 10.1038/s41598-021-89773-5.
The fabrication of different weight percentages of Polycarbonate-Bismuth Oxide composite (PC-BiO), namely 0, 5, 10, 20, 30, 40, and 50 wt%, was done via the mixed-solution method. The dispersion state of the inclusions into the polymeric matrix was studied through XRD and SEM analyses. Also, TGA and DTA analyses were carried out to investigate the thermal properties of the samples. Results showed that increasing the amount of BiO into the polymer matrix shifted the glass transition temperature of the composites towards the lower temperatures. Then, the amount of mass attenuation coefficients of the samples were measured using a CsI(Tl) detector for different gamma rays of Am, Co, Tc, and Ba radioactive sources. It was obtained that increasing the concentration of the BiO fillers in the polycarbonate matrix resulted in increasing the attenuation coefficients of the composites significantly. The attenuation coefficient was enhanced twenty-three times for 50 wt% composite in 59 keV energy, comparing to the pure polycarbonate.
通过混合溶液法制备了不同重量百分比(即0、5、10、20、30、40和50 wt%)的聚碳酸酯 - 氧化铋复合材料(PC - BiO)。通过X射线衍射(XRD)和扫描电子显微镜(SEM)分析研究了夹杂物在聚合物基体中的分散状态。此外,还进行了热重分析(TGA)和差示热分析(DTA)以研究样品的热性能。结果表明,向聚合物基体中增加BiO的量会使复合材料的玻璃化转变温度向更低温度移动。然后,使用碘化铯(铊)探测器针对镅(Am)、钴(Co)、锝(Tc)和钡(Ba)放射性源的不同伽马射线测量了样品的质量衰减系数。结果发现,增加聚碳酸酯基体中BiO填料的浓度会显著提高复合材料的衰减系数。与纯聚碳酸酯相比,50 wt%的复合材料在59 keV能量下的衰减系数提高了23倍。