Tajau Rida, Rohani Rosiah, Alias Mohd Sofian, Mudri Nurul Huda, Abdul Halim Khairul Azhar, Harun Mohd Hamzah, Mat Isa Naurah, Che Ismail Rosley, Muhammad Faisal Sharilla, Talib Marina, Rawi Mohamed Zin Muhammad, Izni Yusoff Izzati, Khairul Zaman Nadiah, Asyila Ilias Iqma
Department of Chemical & Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, UKM Bangi, Selangor 43600, Malaysia.
Radiation Processing Technology Division, Malaysian Nuclear Agency, Bangi, Kajang, Selangor 43000, Malaysia.
Polymers (Basel). 2021 Jun 4;13(11):1865. doi: 10.3390/polym13111865.
In countries that are rich with oil palm, the use of palm oil to produce bio-based acrylates and polyol can be the most eminent raw materials used for developing new and advanced natural polymeric materials involving radiation technique, like coating resins, nanoparticles, scaffold, nanocomposites, and lithography for different branches of the industry. The presence of hydrocarbon chains, carbon double bonds, and ester bonds in palm oil allows it to open up the possibility of fine-tuning its unique structures in the development of novel materials. Cross-linking, reversible addition-fragmentation chain transfer (RAFT), polymerization, grafting, and degradation are among the radiation mechanisms triggered by gamma, electron beam, ultraviolet, or laser irradiation sources. These radiation techniques are widely used in the development of polymeric materials because they are considered as the most versatile, inexpensive, easy, and effective methods. Therefore, this review summarized and emphasized on several recent studies that have reported on emerging radiation processing technologies for the production of radiation curable palm oil-based polymeric materials with a promising future in certain industries and biomedical applications. This review also discusses the rich potential of biopolymeric materials for advanced technology applications.
在盛产油棕的国家，利用棕榈油生产生物基丙烯酸酯和多元醇可以成为开发新型先进天然高分子材料的最主要原材料，这些材料涉及辐射技术，如用于不同工业分支的涂料树脂、纳米颗粒、支架、纳米复合材料和光刻技术。棕榈油中存在的烃链、碳双键和酯键使其在开发新型材料时能够对其独特结构进行微调。交联、可逆加成-断裂链转移（RAFT）、聚合、接枝和降解是由伽马射线、电子束、紫外线或激光辐照源引发的辐射机制。这些辐射技术被广泛用于高分子材料的开发，因为它们被认为是最通用、廉价、简便且有效的方法。因此，本综述总结并强调了近期的几项研究，这些研究报道了用于生产在某些行业和生物医学应用中具有广阔前景的可辐射固化的棕榈油基高分子材料的新兴辐射加工技术。本综述还讨论了生物高分子材料在先进技术应用方面的巨大潜力。
