Shafiq Faizan, Siddique Amna, Pervez Md Nahid, Hassan Mohammad Mahbubul, Naddeo Vincenzo, Cai Yingjie, Hou Aiqin, Xie Kongliang, Khan Muhammad Qamar, Kim Ick-Soo
College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China.
School of Engineering and Technology, National Textile University, Faisalabad 38000, Pakistan.
Materials (Basel). 2021 Oct 6;14(19):5850. doi: 10.3390/ma14195850.
The aerial parts of the Argy Worm Wood (AWW) plant have been used in different Chinese foods as a colorant and a taste enhancer for a long time. Despite its application as a food colorant, it has rarely been considered for the coloration of textiles. Keeping in mind the variation in color strength due to the change in phytochemical contents by seasonal change and other variables, the extraction of AWW aerial parts was optimized using the Taguchi method. Optimization was performed on the basis of total phytochemical contents (phenols, flavonoids, and tannins) in the extracted solutions. For this purpose, two different solvent systems, namely sodium hydroxide/water (NaOH/water) and ethanol/water (EtOH/water), were applied through a simple aqueous extraction method at varying levels of solvent concentration, and extraction temperature and duration. Maximum phytochemicals yield of 21.96% was obtained using NaOH/water system with 9 g/L NaOH/water at 85 °C for 20 min and 25.5% with 75% aqueous ethanol at 85 °C for 40 min. Optimized extracts were characterized by UV-Vis and FTIR spectrophotometry, which showed the presence of multiple phytochemicals in the extracts. The dyeing temperature and time were also optimized. Dyed cotton fabrics showed medium to high colorfastness to washing and excellent antibacterial and UV radiation absorption properties. The effect of pre-mordanting with salts of iron and copper was also studied on the color fastness properties. Cotton fabrics dyed with two different solvent system extracts displayed various shades of brown with NaOH/water, and green with aqueous ethanol with and without pre-mordanting. The present study provides the textile industry with a promising source of functional bio-colorant and a value-adding approach for the AWW plant industry.
长期以来,艾草(AWW)植株的地上部分一直被用作不同中式食品的着色剂和风味增强剂。尽管它被用作食品着色剂,但很少被考虑用于纺织品染色。考虑到由于季节变化和其他变量导致植物化学成分变化而引起的颜色强度差异,采用田口方法对艾草地上部分的提取进行了优化。优化是基于提取液中的总植物化学成分(酚类、黄酮类和单宁类)进行的。为此,通过简单的水提取方法,在不同的溶剂浓度、提取温度和时间水平下,应用了两种不同的溶剂体系,即氢氧化钠/水(NaOH/水)和乙醇/水(EtOH/水)。使用NaOH/水体系,在85℃下用9 g/L NaOH/水提取20分钟,植物化学成分的最大产率为21.96%;使用75%乙醇水溶液,在85℃下提取40分钟,产率为25.5%。通过紫外-可见光谱和傅里叶变换红外光谱对优化后的提取物进行了表征,结果表明提取物中存在多种植物化学成分。还对染色温度和时间进行了优化。染色后的棉织物对洗涤具有中到高的色牢度,并具有优异的抗菌和紫外线吸收性能。还研究了用铁盐和铜盐预媒染对色牢度性能的影响。用两种不同溶剂体系提取物染色的棉织物,用NaOH/水染色呈现出各种棕色色调,用乙醇水溶液染色,无论有无预媒染均呈现绿色。本研究为纺织工业提供了一种有前景的功能性生物着色剂来源,也为艾草产业提供了一种增值方法。